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Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry”
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dc.contributor.author | Bidal, Yannick Daniel | |
dc.contributor.author | Lesieur, Mathieu | |
dc.contributor.author | Melaimi, Mohand | |
dc.contributor.author | Nahra, Fady | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Athukorala Arachchige, Kasun Sankalpa | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Bertrand, Guy | |
dc.contributor.author | Cazin, Catherine S.J. | |
dc.date.accessioned | 2016-10-12T23:33:30Z | |
dc.date.available | 2016-10-12T23:33:30Z | |
dc.date.issued | 2015-10-12 | |
dc.identifier | 212891400 | |
dc.identifier | 279b1936-a0e4-4501-82b2-0af471ed8e19 | |
dc.identifier | 84944930085 | |
dc.identifier | 000363507400021 | |
dc.identifier.citation | Bidal , Y D , Lesieur , M , Melaimi , M , Nahra , F , Cordes , D B , Athukorala Arachchige , K S , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry” ' , Advanced Synthesis & Catalysis , vol. 357 , no. 14-15 , pp. 3155–3161 . https://doi.org/10.1002/adsc.201500453 | en |
dc.identifier.issn | 1615-4150 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023996 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861619 | |
dc.identifier.uri | https://hdl.handle.net/10023/9653 | |
dc.description | The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support. | en |
dc.description.abstract | The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes. | |
dc.format.extent | 907732 | |
dc.language.iso | eng | |
dc.relation.ispartof | Advanced Synthesis & Catalysis | en |
dc.subject | Copper | en |
dc.subject | Abnormal carbene | en |
dc.subject | Remote carbene | en |
dc.subject | N-heterocyclic carbene | en |
dc.subject | Click chemistry | en |
dc.subject | [3+2] cycloaddition | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry” | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1002/adsc.201500453 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-10-12 | |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/adsc.201500453/suppinfo | en |
dc.identifier.grantnumber | UF100691 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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