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dc.contributor.authorBidal, Yannick Daniel
dc.contributor.authorLesieur, Mathieu
dc.contributor.authorMelaimi, Mohand
dc.contributor.authorNahra, Fady
dc.contributor.authorCordes, David Bradford
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBertrand, Guy
dc.contributor.authorCazin, Catherine S.J.
dc.identifier.citationBidal , Y D , Lesieur , M , Melaimi , M , Nahra , F , Cordes , D B , Athukorala Arachchige , K S , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry” ' , Advanced Synthesis & Catalysis , vol. 357 , no. 14-15 , pp. 3155–3161 .
dc.identifier.otherPURE: 212891400
dc.identifier.otherPURE UUID: 279b1936-a0e4-4501-82b2-0af471ed8e19
dc.identifier.otherScopus: 84944930085
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023996
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861619
dc.identifier.otherWOS: 000363507400021
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.en
dc.description.abstractThe synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.
dc.relation.ispartofAdvanced Synthesis & Catalysisen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectAbnormal carbeneen
dc.subjectRemote carbeneen
dc.subjectN-heterocyclic carbeneen
dc.subjectClick chemistryen
dc.subject[3+2] cycloadditionen
dc.subjectQD Chemistryen
dc.titleCopper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry”en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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