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dc.contributor.authorBidal, Yannick Daniel
dc.contributor.authorLesieur, Mathieu
dc.contributor.authorMelaimi, Mohand
dc.contributor.authorNahra, Fady
dc.contributor.authorCordes, David Bradford
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBertrand, Guy
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2016-10-12T23:33:30Z
dc.date.available2016-10-12T23:33:30Z
dc.date.issued2015-10-12
dc.identifier212891400
dc.identifier279b1936-a0e4-4501-82b2-0af471ed8e19
dc.identifier84944930085
dc.identifier000363507400021
dc.identifier.citationBidal , Y D , Lesieur , M , Melaimi , M , Nahra , F , Cordes , D B , Athukorala Arachchige , K S , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry” ' , Advanced Synthesis & Catalysis , vol. 357 , no. 14-15 , pp. 3155–3161 . https://doi.org/10.1002/adsc.201500453en
dc.identifier.issn1615-4150
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023996
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861619
dc.identifier.urihttps://hdl.handle.net/10023/9653
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.en
dc.description.abstractThe synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.
dc.format.extent907732
dc.language.isoeng
dc.relation.ispartofAdvanced Synthesis & Catalysisen
dc.subjectCopperen
dc.subjectAbnormal carbeneen
dc.subjectRemote carbeneen
dc.subjectN-heterocyclic carbeneen
dc.subjectClick chemistryen
dc.subject[3+2] cycloadditionen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleCopper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry”en
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/adsc.201500453
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-10-12
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/adsc.201500453/suppinfoen
dc.identifier.grantnumberUF100691en
dc.identifier.grantnumberEP/K039210/1en


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