Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry”
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Date
12/10/2015Author
Grant ID
UF100691
EP/K039210/1
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The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.
Citation
Bidal , Y D , Lesieur , M , Melaimi , M , Nahra , F , Cordes , D B , Athukorala Arachchige , K S , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in “click chemistry” ' , Advanced Synthesis & Catalysis , vol. 357 , no. 14-15 , pp. 3155–3161 . https://doi.org/10.1002/adsc.201500453
Publication
Advanced Synthesis & Catalysis
Status
Peer reviewed
ISSN
1615-4150Type
Journal article
Description
The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.Collections
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