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Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

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Nolan_2015_JOC_Evaluation_AM.pdf (583.4Kb)
Date
15/03/2015
Author
Manzini, Simone
Urbina Blanco, Cesar
Nelson, David James
Poater, Albert
Lebl, Tomas
Meiries, Sebastien Michel Bernard
Slawin, Alexandra Martha Zoya
Falivene, Laura
Cavallo, Luigi
Nolan, Steven Patrick
Keywords
Density functional theory
N-Heterocyclic carbine
Olefin metathesis
Ruthenium
QD Chemistry
DAS
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Abstract
The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
Citation
Manzini , S , Urbina Blanco , C , Nelson , D J , Poater , A , Lebl , T , Meiries , S M B , Slawin , A M Z , Falivene , L , Cavallo , L & Nolan , S P 2015 , ' Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene ' , Journal of Organometallic Chemistry , vol. 780 , pp. 43-48 . https://doi.org/10.1016/j.jorganchem.2014.12.040
Publication
Journal of Organometallic Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.1016/j.jorganchem.2014.12.040
ISSN
0022-328X
Type
Journal article
Rights
© 2015 Elsevier B.V. All rights reserved. This is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, volume 780 (2015), DOI: 10.1016/j.jorganchem.2014.12.040
Description
SPN thanks the European Research Council(227817) (Advanced Investigator Award ‘FUNCAT’), the EU(CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ramón y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011-293900).
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  • University of St Andrews Research
URL
http://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd003
http://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd002
URI
http://hdl.handle.net/10023/7995

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