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Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

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dc.contributor.authorManzini, Simone
dc.contributor.authorUrbina Blanco, Cesar
dc.contributor.authorNelson, David James
dc.contributor.authorPoater, Albert
dc.contributor.authorLebl, Tomas
dc.contributor.authorMeiries, Sebastien Michel Bernard
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorFalivene, Laura
dc.contributor.authorCavallo, Luigi
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2016-01-09T00:12:06Z
dc.date.available2016-01-09T00:12:06Z
dc.date.issued2015-03-15
dc.identifier.citationManzini , S , Urbina Blanco , C , Nelson , D J , Poater , A , Lebl , T , Meiries , S M B , Slawin , A M Z , Falivene , L , Cavallo , L & Nolan , S P 2015 , ' Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene ' , Journal of Organometallic Chemistry , vol. 780 , pp. 43-48 . https://doi.org/10.1016/j.jorganchem.2014.12.040en
dc.identifier.issn0022-328X
dc.identifier.otherPURE: 161422739
dc.identifier.otherPURE UUID: 195e4e4b-447f-42ab-92c6-7a45c85a59c8
dc.identifier.otherScopus: 84921522424
dc.identifier.otherWOS: 000349903700007
dc.identifier.otherORCID: /0000-0002-0269-3221/work/48131732
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861325
dc.identifier.urihttp://hdl.handle.net/10023/7995
dc.descriptionSPN thanks the European Research Council(227817) (Advanced Investigator Award ‘FUNCAT’), the EU(CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ramón y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011-293900).en
dc.description.abstractThe commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.rights© 2015 Elsevier B.V. All rights reserved. This is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, volume 780 (2015), DOI: 10.1016/j.jorganchem.2014.12.040en
dc.subjectDensity functional theoryen
dc.subjectN-Heterocyclic carbineen
dc.subjectOlefin metathesisen
dc.subjectRutheniumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleEvaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbeneen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.jorganchem.2014.12.040
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-01-09
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd003en
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd002en


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