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Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

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dc.contributor.authorManzini, Simone
dc.contributor.authorUrbina Blanco, Cesar
dc.contributor.authorNelson, David James
dc.contributor.authorPoater, Albert
dc.contributor.authorLebl, Tomas
dc.contributor.authorMeiries, Sebastien Michel Bernard
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorFalivene, Laura
dc.contributor.authorCavallo, Luigi
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2016-01-09T00:12:06Z
dc.date.available2016-01-09T00:12:06Z
dc.date.issued2015-03-15
dc.identifier161422739
dc.identifier195e4e4b-447f-42ab-92c6-7a45c85a59c8
dc.identifier84921522424
dc.identifier000349903700007
dc.identifier.citationManzini , S , Urbina Blanco , C , Nelson , D J , Poater , A , Lebl , T , Meiries , S M B , Slawin , A M Z , Falivene , L , Cavallo , L & Nolan , S P 2015 , ' Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene ' , Journal of Organometallic Chemistry , vol. 780 , pp. 43-48 . https://doi.org/10.1016/j.jorganchem.2014.12.040en
dc.identifier.issn0022-328X
dc.identifier.otherORCID: /0000-0002-0269-3221/work/48131732
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861325
dc.identifier.urihttps://hdl.handle.net/10023/7995
dc.descriptionSPN thanks the European Research Council(227817) (Advanced Investigator Award ‘FUNCAT’), the EU(CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ramón y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011-293900).en
dc.description.abstractThe commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
dc.format.extent7
dc.format.extent597448
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.subjectDensity functional theoryen
dc.subjectN-Heterocyclic carbineen
dc.subjectOlefin metathesisen
dc.subjectRutheniumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleEvaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbeneen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.sponsorEuropean Commissionen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.jorganchem.2014.12.040
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-01-09
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd003en
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15000066#appd002en
dc.identifier.grantnumberFP7-227817 FUNCATen
dc.identifier.grantnumberCP-FP 211468-2 EUMETen
dc.identifier.grantnumberEP/K039210/1en
dc.identifier.grantnumberEP/K031252/1en


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