Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2
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Date
10/06/1999Keywords
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Abstract
Deprotonation of (2-diphenylphosphino)benzeneamine with BuLi followed by reaction with ClPPh2 in THF gave Ph2PNHC6H4PPh2 in good yields. The new unsymmetrical ligand has been incorporated into a number of complexes [[Rh(Ph2PNHC6H4PPh2)(cod)][ClO4] 2, RhCl2(eta(5)-C4Me5) (Ph2PNHC6H4PPh2-P-(N)) 3, [RhCl(eta(5)-C5Me5) (Ph2PNHC6H4PPh2-P(N)P)][Cl] 4, IrCl2(eta(5)-C5Me5) (Ph2PNHC6H4PPh2P(N)) 5, RuCl2(eta(6)-(MeC6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N)) 6, [RuCl(eta(6)-Me-(C6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 7, RuCl2(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N)) 8, [RuCl(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 9, RuCl2(eta(3):eta(3)-C10H16) (Ph2PNHC6H4PPh2-P-(N)) 10, OsCl2(eta(6)-(MeC6H4Pr)-Pr-i)(Ph2NHPC6H4PPh2-P-(N)) 11] to demonstrate its coordination behaviour as a monodentate or as a chelate ligand. The X-ray structures of for 5, 9 and 10 are reported. (C) 1999 Elsevier Science S.A. All rights reserved.
Citation
Aucott , SM , Slawin , A M Z & Woollins , J D 1999 , ' Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph 2 PNHC 6 H 4 PPh 2 ' , Journal of Organometallic Chemistry , vol. 582 , pp. 83-89 . https://doi.org/10.1016/S0022-328X(98)01189-9
Publication
Journal of Organometallic Chemistry
Status
Peer reviewed
ISSN
0022-328XType
Journal article
Rights
© 1999 Elsevier Science S.A. All rights reserved. This is the author’s version of a work that was accepted for publication in the Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 582, 1 (1999) DOI 10.1016/S0022-328X(98)01189-9
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