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Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2

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dc.contributor.authorAucott, SM
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, John Derek
dc.date.accessioned2014-07-01T09:01:00Z
dc.date.available2014-07-01T09:01:00Z
dc.date.issued1999-06-10
dc.identifier.citationAucott , SM , Slawin , A M Z & Woollins , J D 1999 , ' Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph 2 PNHC 6 H 4 PPh 2 ' , Journal of Organometallic Chemistry , vol. 582 , pp. 83-89 . https://doi.org/10.1016/S0022-328X(98)01189-9en
dc.identifier.issn0022-328X
dc.identifier.otherPURE: 153805
dc.identifier.otherPURE UUID: 274a17c1-69d3-4334-a3c1-be097c5bbb46
dc.identifier.otherWOS: 000081007800013
dc.identifier.otherScopus: 0002373462
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862035
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779297
dc.identifier.urihttps://hdl.handle.net/10023/4933
dc.description.abstractDeprotonation of (2-diphenylphosphino)benzeneamine with BuLi followed by reaction with ClPPh2 in THF gave Ph2PNHC6H4PPh2 in good yields. The new unsymmetrical ligand has been incorporated into a number of complexes [[Rh(Ph2PNHC6H4PPh2)(cod)][ClO4] 2, RhCl2(eta(5)-C4Me5) (Ph2PNHC6H4PPh2-P-(N)) 3, [RhCl(eta(5)-C5Me5) (Ph2PNHC6H4PPh2-P(N)P)][Cl] 4, IrCl2(eta(5)-C5Me5) (Ph2PNHC6H4PPh2P(N)) 5, RuCl2(eta(6)-(MeC6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N)) 6, [RuCl(eta(6)-Me-(C6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 7, RuCl2(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N)) 8, [RuCl(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 9, RuCl2(eta(3):eta(3)-C10H16) (Ph2PNHC6H4PPh2-P-(N)) 10, OsCl2(eta(6)-(MeC6H4Pr)-Pr-i)(Ph2NHPC6H4PPh2-P-(N)) 11] to demonstrate its coordination behaviour as a monodentate or as a chelate ligand. The X-ray structures of for 5, 9 and 10 are reported. (C) 1999 Elsevier Science S.A. All rights reserved.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.rights© 1999 Elsevier Science S.A. All rights reserved. This is the author’s version of a work that was accepted for publication in the Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 582, 1 (1999) DOI 10.1016/S0022-328X(98)01189-9en
dc.subjectPhosphineen
dc.subjectX-ray structureen
dc.subjectHeterocycleen
dc.subjectTransition metalen
dc.subjectComplexen
dc.subjectCoordination chemistryen
dc.subjectBonden
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titlePreparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2en
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/S0022-328X(98)01189-9
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.scopus.com/inward/record.url?scp=0002373462&partnerID=8YFLogxKen


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