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dc.contributor.authorAucott, SM
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, John Derek
dc.date.accessioned2014-07-01T09:01:00Z
dc.date.available2014-07-01T09:01:00Z
dc.date.issued1999-06-10
dc.identifier153805
dc.identifier274a17c1-69d3-4334-a3c1-be097c5bbb46
dc.identifier000081007800013
dc.identifier0002373462
dc.identifier.citationAucott , SM , Slawin , A M Z & Woollins , J D 1999 , ' Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph 2 PNHC 6 H 4 PPh 2 ' , Journal of Organometallic Chemistry , vol. 582 , pp. 83-89 . https://doi.org/10.1016/S0022-328X(98)01189-9en
dc.identifier.issn0022-328X
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862035
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779297
dc.identifier.urihttps://hdl.handle.net/10023/4933
dc.description.abstractDeprotonation of (2-diphenylphosphino)benzeneamine with BuLi followed by reaction with ClPPh2 in THF gave Ph2PNHC6H4PPh2 in good yields. The new unsymmetrical ligand has been incorporated into a number of complexes [[Rh(Ph2PNHC6H4PPh2)(cod)][ClO4] 2, RhCl2(eta(5)-C4Me5) (Ph2PNHC6H4PPh2-P-(N)) 3, [RhCl(eta(5)-C5Me5) (Ph2PNHC6H4PPh2-P(N)P)][Cl] 4, IrCl2(eta(5)-C5Me5) (Ph2PNHC6H4PPh2P(N)) 5, RuCl2(eta(6)-(MeC6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N)) 6, [RuCl(eta(6)-Me-(C6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 7, RuCl2(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N)) 8, [RuCl(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 9, RuCl2(eta(3):eta(3)-C10H16) (Ph2PNHC6H4PPh2-P-(N)) 10, OsCl2(eta(6)-(MeC6H4Pr)-Pr-i)(Ph2NHPC6H4PPh2-P-(N)) 11] to demonstrate its coordination behaviour as a monodentate or as a chelate ligand. The X-ray structures of for 5, 9 and 10 are reported. (C) 1999 Elsevier Science S.A. All rights reserved.
dc.format.extent7
dc.format.extent380416
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.subjectPhosphineen
dc.subjectX-ray structureen
dc.subjectHeterocycleen
dc.subjectTransition metalen
dc.subjectComplexen
dc.subjectCoordination chemistryen
dc.subjectBonden
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titlePreparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/S0022-328X(98)01189-9
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.scopus.com/inward/record.url?scp=0002373462&partnerID=8YFLogxKen


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