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Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2
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dc.contributor.author | Aucott, SM | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, John Derek | |
dc.date.accessioned | 2014-07-01T09:01:00Z | |
dc.date.available | 2014-07-01T09:01:00Z | |
dc.date.issued | 1999-06-10 | |
dc.identifier | 153805 | |
dc.identifier | 274a17c1-69d3-4334-a3c1-be097c5bbb46 | |
dc.identifier | 000081007800013 | |
dc.identifier | 0002373462 | |
dc.identifier.citation | Aucott , SM , Slawin , A M Z & Woollins , J D 1999 , ' Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph 2 PNHC 6 H 4 PPh 2 ' , Journal of Organometallic Chemistry , vol. 582 , pp. 83-89 . https://doi.org/10.1016/S0022-328X(98)01189-9 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862035 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779297 | |
dc.identifier.uri | https://hdl.handle.net/10023/4933 | |
dc.description.abstract | Deprotonation of (2-diphenylphosphino)benzeneamine with BuLi followed by reaction with ClPPh2 in THF gave Ph2PNHC6H4PPh2 in good yields. The new unsymmetrical ligand has been incorporated into a number of complexes [[Rh(Ph2PNHC6H4PPh2)(cod)][ClO4] 2, RhCl2(eta(5)-C4Me5) (Ph2PNHC6H4PPh2-P-(N)) 3, [RhCl(eta(5)-C5Me5) (Ph2PNHC6H4PPh2-P(N)P)][Cl] 4, IrCl2(eta(5)-C5Me5) (Ph2PNHC6H4PPh2P(N)) 5, RuCl2(eta(6)-(MeC6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N)) 6, [RuCl(eta(6)-Me-(C6H4Pr)-Pr-i) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 7, RuCl2(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N)) 8, [RuCl(eta(6)-C6Me6) (Ph2PNHC6H4PPh2-P-(N),P)][BF4] 9, RuCl2(eta(3):eta(3)-C10H16) (Ph2PNHC6H4PPh2-P-(N)) 10, OsCl2(eta(6)-(MeC6H4Pr)-Pr-i)(Ph2NHPC6H4PPh2-P-(N)) 11] to demonstrate its coordination behaviour as a monodentate or as a chelate ligand. The X-ray structures of for 5, 9 and 10 are reported. (C) 1999 Elsevier Science S.A. All rights reserved. | |
dc.format.extent | 7 | |
dc.format.extent | 380416 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Organometallic Chemistry | en |
dc.subject | Phosphine | en |
dc.subject | X-ray structure | en |
dc.subject | Heterocycle | en |
dc.subject | Transition metal | en |
dc.subject | Complex | en |
dc.subject | Coordination chemistry | en |
dc.subject | Bond | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Preparation and organometallic complexes of the new unsymmetrical Ligand: Ph2PNHC6H4PPh2 | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/S0022-328X(98)01189-9 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?scp=0002373462&partnerID=8YFLogxK | en |
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