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An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.
McGeachie , L J R , Carpenter-Warren , C L , Cordes , D B , Buehl , M , Gray , S J , Hua , G , Slawin , A M Z & Woollins , J D 2020 , ' Thionylimido complexes ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. Early View . https://doi.org/10.1002/zaac.202000238
Zeitschrift für Anorganische und Allgemeine Chemie
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