Thionylimido complexes
Abstract
An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.
Citation
McGeachie , L J R , Carpenter-Warren , C L , Cordes , D B , Buehl , M , Gray , S J , Hua , G , Slawin , A M Z & Woollins , J D 2020 , ' Thionylimido complexes ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 646 , no. 22 , pp. 1795-1798 . https://doi.org/10.1002/zaac.202000238
Publication
Zeitschrift für Anorganische und Allgemeine Chemie
Status
Peer reviewed
ISSN
0044-2313Type
Journal article
Collections
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