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Thionylimido complexes

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dc.contributor.authorMcGeachie, Liam J. R.
dc.contributor.authorCarpenter-Warren, Cameron L.
dc.contributor.authorCordes, David B.
dc.contributor.authorBuehl, Michael
dc.contributor.authorGray, Steven J.
dc.contributor.authorHua, Guoxiong
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2020-08-13T09:30:02Z
dc.date.available2020-08-13T09:30:02Z
dc.date.issued2020-11-27
dc.identifier269325287
dc.identifier2932154c-2bc2-405a-8618-088ddadf4d39
dc.identifier85089312602
dc.identifier000558509400001
dc.identifier.citationMcGeachie , L J R , Carpenter-Warren , C L , Cordes , D B , Buehl , M , Gray , S J , Hua , G , Slawin , A M Z & Woollins , J D 2020 , ' Thionylimido complexes ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 646 , no. 22 , pp. 1795-1798 . https://doi.org/10.1002/zaac.202000238en
dc.identifier.issn0044-2313
dc.identifier.otherORCID: /0000-0002-1095-7143/work/78891477
dc.identifier.otherORCID: /0000-0002-9527-6418/work/78891505
dc.identifier.otherORCID: /0000-0002-1498-9652/work/78891537
dc.identifier.otherORCID: /0000-0002-5366-9168/work/78891545
dc.identifier.urihttps://hdl.handle.net/10023/20458
dc.description.abstractAn improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.
dc.format.extent5
dc.format.extent406388
dc.language.isoeng
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen
dc.subjectThionylimideen
dc.subjectThiazateen
dc.subjectComplexen
dc.subjectAntimonyen
dc.subjectX-ray structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleThionylimido complexesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/zaac.202000238
dc.description.statusPeer revieweden


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