An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand
Abstract
A cadmium-mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O-H···I hydrogen bonds, and these interactions lead to the formation of an R44 ${\rm{R}} $ (22) motif.
Citation
Mardani , Z , Kazemshoar-Duzduzani , R , Moeini , K , Darroudi , M , Carpenter-Warren , C , Slawin , A M Z & Derek Woollins , J 2018 , ' An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand ' , Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences , vol. 73 , no. 12 , pp. 959-963 . https://doi.org/10.1515/znb-2018-0158
Publication
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Status
Peer reviewed
ISSN
0932-0776Type
Journal article
Rights
Copyright © 2018 Walter de Gruyter GmbH, Berlin/Boston. This work is made available online in accordance with the publisher’s policies. This is the final published version of the work, which was originally published at: https://doi.org/10.1515/znb-2018-0158
Description
This study was supported financially by the Iran National Science Foundation (INSF).Collections
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