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dc.contributor.authorMardani, Zahra
dc.contributor.authorKazemshoar-Duzduzani, Reza
dc.contributor.authorMoeini, Keyvan
dc.contributor.authorDarroudi, Majid
dc.contributor.authorCarpenter-Warren, Cameron
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorDerek Woollins, J.
dc.date.accessioned2019-11-09T00:37:04Z
dc.date.available2019-11-09T00:37:04Z
dc.date.issued2018-12-19
dc.identifier.citationMardani , Z , Kazemshoar-Duzduzani , R , Moeini , K , Darroudi , M , Carpenter-Warren , C , Slawin , A M Z & Derek Woollins , J 2018 , ' An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand ' , Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences , vol. 73 , no. 12 , pp. 959-963 . https://doi.org/10.1515/znb-2018-0158en
dc.identifier.issn0932-0776
dc.identifier.otherPURE: 256773614
dc.identifier.otherPURE UUID: f03df372-2b9e-4ae9-b9d2-9832d8a8dc4e
dc.identifier.otherScopus: 85056526552
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861655
dc.identifier.otherORCID: /0000-0002-1498-9652/work/59464677
dc.identifier.otherWOS: 000451338700001
dc.identifier.urihttps://hdl.handle.net/10023/18891
dc.descriptionThis study was supported financially by the Iran National Science Foundation (INSF).en
dc.description.abstractA cadmium-mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O-H···I hydrogen bonds, and these interactions lead to the formation of an R44 ${\rm{R}} $ (22) motif.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofZeitschrift fur Naturforschung - Section B Journal of Chemical Sciencesen
dc.rightsCopyright © 2018 Walter de Gruyter GmbH, Berlin/Boston. This work is made available online in accordance with the publisher’s policies. This is the final published version of the work, which was originally published at: https://doi.org/10.1515/znb-2018-0158en
dc.subjectCd/Hg mixed-metal complexen
dc.subjectdiastereomeren
dc.subjectX-ray crystal structureen
dc.subjectβ-amino alcoholen
dc.subjectQD Chemistryen
dc.subjectChemistry(all)en
dc.subjectNDASen
dc.subject.lccQDen
dc.titleAn ionic Cd/Hg mixed-metal complex with an aminoalcohol liganden
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1515/znb-2018-0158
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-11-09


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