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An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand

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dc.contributor.authorMardani, Zahra
dc.contributor.authorKazemshoar-Duzduzani, Reza
dc.contributor.authorMoeini, Keyvan
dc.contributor.authorDarroudi, Majid
dc.contributor.authorCarpenter-Warren, Cameron
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorDerek Woollins, J.
dc.date.accessioned2019-11-09T00:37:04Z
dc.date.available2019-11-09T00:37:04Z
dc.date.issued2018-12-19
dc.identifier256773614
dc.identifierf03df372-2b9e-4ae9-b9d2-9832d8a8dc4e
dc.identifier85056526552
dc.identifier000451338700001
dc.identifier.citationMardani , Z , Kazemshoar-Duzduzani , R , Moeini , K , Darroudi , M , Carpenter-Warren , C , Slawin , A M Z & Derek Woollins , J 2018 , ' An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand ' , Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences , vol. 73 , no. 12 , pp. 959-963 . https://doi.org/10.1515/znb-2018-0158en
dc.identifier.issn0932-0776
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861655
dc.identifier.otherORCID: /0000-0002-1498-9652/work/59464677
dc.identifier.urihttps://hdl.handle.net/10023/18891
dc.descriptionThis study was supported financially by the Iran National Science Foundation (INSF).en
dc.description.abstractA cadmium-mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O-H···I hydrogen bonds, and these interactions lead to the formation of an R44 ${\rm{R}} $ (22) motif.
dc.format.extent5
dc.format.extent380995
dc.language.isoeng
dc.relation.ispartofZeitschrift fur Naturforschung - Section B Journal of Chemical Sciencesen
dc.subjectCd/Hg mixed-metal complexen
dc.subjectdiastereomeren
dc.subjectX-ray crystal structureen
dc.subjectβ-amino alcoholen
dc.subjectQD Chemistryen
dc.subjectChemistry(all)en
dc.subjectNDASen
dc.subject.lccQDen
dc.titleAn ionic Cd/Hg mixed-metal complex with an aminoalcohol liganden
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1515/znb-2018-0158
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-11-09


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