Files in this item
Remarkable co-catalyst effects on the enantioselective hydrogenation of unfunctionalised enamines : both enantiomers of product from the same enantiomer of catalyst
Item metadata
dc.contributor.author | Tin, Sergey | |
dc.contributor.author | Fanjul, Tamara | |
dc.contributor.author | Clarke, Matthew L. | |
dc.date.accessioned | 2016-12-08T00:32:58Z | |
dc.date.available | 2016-12-08T00:32:58Z | |
dc.date.issued | 2016-02-07 | |
dc.identifier | 241040700 | |
dc.identifier | d4507c76-4ddf-4ef3-af4a-e080538a1524 | |
dc.identifier | 84957562576 | |
dc.identifier | 000369533400008 | |
dc.identifier.citation | Tin , S , Fanjul , T & Clarke , M L 2016 , ' Remarkable co-catalyst effects on the enantioselective hydrogenation of unfunctionalised enamines : both enantiomers of product from the same enantiomer of catalyst ' , Catalysis Science & Technology , vol. 6 , no. 3 , pp. 677-680 . https://doi.org/10.1039/C5CY02051D | en |
dc.identifier.issn | 2044-4753 | |
dc.identifier.other | Bibtex: urn:0234c9f6219646ac3cf0c585fadbc691 | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464644 | |
dc.identifier.uri | https://hdl.handle.net/10023/9948 | |
dc.description.abstract | During studies on the enantioselective hydrogenation of unfunctionalised enamines, a very surprising switch in enantiopreference was observed; [((R,R)-Et-DUPHOS)-Rh(COD)]BF4 hydrogenates an enamine to give (R)-amine with up to 73% ee, but when iodine is added as a co-catalyst, the (S)-amine is formed with up to 61% ee. Mechanistic studies implicate a protonation-iminium ion reduction pathway. | |
dc.format.extent | 4 | |
dc.format.extent | 582349 | |
dc.language.iso | eng | |
dc.relation.ispartof | Catalysis Science & Technology | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Remarkable co-catalyst effects on the enantioselective hydrogenation of unfunctionalised enamines : both enantiomers of product from the same enantiomer of catalyst | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C5CY02051D | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-12-07 | |
dc.identifier.url | http://www.rsc.org/suppdata/c5/cy/c5cy02051d/c5cy02051d1.pdf | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.