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α-Methylenation of methyl propanoate via catalytic dehydrogenation of methanol

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dc.contributor.authorLorusso, Patrizia
dc.contributor.authorCoetzee, Jacorien
dc.contributor.authorEastham, Graham
dc.contributor.authorCole-Hamilton, David John
dc.date.accessioned2016-11-11T00:33:39Z
dc.date.available2016-11-11T00:33:39Z
dc.date.issued2016-01-07
dc.identifier.citationLorusso , P , Coetzee , J , Eastham , G & Cole-Hamilton , D J 2016 , ' α-Methylenation of methyl propanoate via catalytic dehydrogenation of methanol ' , ChemCatChem , vol. 8 , no. 1 , pp. 222–227 . https://doi.org/10.1002/cctc.201500763en
dc.identifier.issn1867-3880
dc.identifier.otherPURE: 234893329
dc.identifier.otherPURE UUID: 91927b5c-4f90-4116-b8c8-815c8bbaec3d
dc.identifier.otherScopus: 84955192858
dc.identifier.otherWOS: 000370031400029
dc.identifier.urihttps://hdl.handle.net/10023/9802
dc.description.abstractA one-pot system for the conversion of methyl propanoate (MeP) to methyl methacrylate (MMA) has been investigated. In particular, this study is focused on the possibility of performing catalytic dehydrogenation of methanol for the in situ production of anhydrous formaldehyde, which is then consumed in a one-pot base-catalysed condensation with MeP to afford methyl 3-hydroxy-2-methylpropanoate, which spontaneously dehydrogenates to MMA, some of which is subsequently hydrogenated to methyl 2-methypropanoate (MiBu).
dc.language.isoeng
dc.relation.ispartofChemCatChemen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-820227.html#terms. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/cctc.201500763en
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-820227.html#terms. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/cctc.201500763en
dc.subjectAnhydrous formaldehydeen
dc.subjectDehydrogenationen
dc.subjectMethyl methacrylateen
dc.subjectOne-pot systemen
dc.subjectRutheniumen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleα-Methylenation of methyl propanoate via catalytic dehydrogenation of methanolen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1002/cctc.201500763
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-11-10
dc.identifier.urlhttp://onlinelibrary.wiley.com/wol1/doi/10.1002/cctc.201500763/suppinfoen


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