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dc.contributor.authorNejman, Phillip S.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorKilian, Petr
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2016-10-27T14:30:40Z
dc.date.available2016-10-27T14:30:40Z
dc.date.issued2016-10-11
dc.identifier.citationNejman , P S , Slawin , A M Z , Kilian , P & Woollins , J D 2016 , ' Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation ' Cogent Chemistry , vol. 2 , no. 1 , 1245900 . DOI: 10.1080/23312009.2016.1245900en
dc.identifier.issn2331-2009
dc.identifier.otherPURE: 246780800
dc.identifier.otherPURE UUID: d6e2eba3-2767-4510-8e63-ad98661d0268
dc.identifier.otherRIS: urn:E93C5CC986756C73FA530DB67E0CB1E7
dc.identifier.urihttp://hdl.handle.net/10023/9715
dc.identifier.urihttp://www.tandfonline.com/doi/abs/10.1080/23312009.2016.1245900en
dc.description.abstractA series of rhodium(III) half sandwich complexes of the type [Cp*Rh(PMe3)(S—R—S)]; S—R—S = naphthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate, [1,1′-biphenyl]-2,2′-dithiolate and [2,2′-binaphthalene]-1,1′-dithiolate are reported. In the case of [2,2′-binaphthalene]-1,1′-dithiolate this represents an infrequent example of a metal complex containing this ligand. All the complexes have been fully characterised using multinuclear NMR spectroscopy and single crystal X-ray diffraction. The single crystal X-ray structure of the starting material [Cp*Rh(PMe3)Br2] ( 1 ) is also reported for the first time.en
dc.language.isoeng
dc.relation.ispartofCogent Chemistryen
dc.rights© 2016 The Authors. This open access article is distributed under a Creative Commons Attribution (CC-BY) 4.0 license.en
dc.subjectDithiolatesen
dc.subjectHalf sandwichen
dc.subjectComplexationen
dc.subjectRhodiumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleVarying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigationen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1080/23312009.2016.1245900
dc.description.statusPeer revieweden


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