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Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation
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dc.contributor.author | Nejman, Phillip S. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Kilian, Petr | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2016-10-27T14:30:40Z | |
dc.date.available | 2016-10-27T14:30:40Z | |
dc.date.issued | 2016-10-11 | |
dc.identifier.citation | Nejman , P S , Slawin , A M Z , Kilian , P & Woollins , J D 2016 , ' Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation ' , Cogent Chemistry , vol. 2 , no. 1 , 1245900 . https://doi.org/10.1080/23312009.2016.1245900 | en |
dc.identifier.issn | 2331-2009 | |
dc.identifier.other | PURE: 246780800 | |
dc.identifier.other | PURE UUID: d6e2eba3-2767-4510-8e63-ad98661d0268 | |
dc.identifier.other | RIS: urn:E93C5CC986756C73FA530DB67E0CB1E7 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861645 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/58285403 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779155 | |
dc.identifier.other | WOS: 000387053600001 | |
dc.identifier.uri | https://hdl.handle.net/10023/9715 | |
dc.description.abstract | A series of rhodium(III) half sandwich complexes of the type [Cp*Rh(PMe3)(S—R—S)]; S—R—S = naphthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate, [1,1′-biphenyl]-2,2′-dithiolate and [2,2′-binaphthalene]-1,1′-dithiolate are reported. In the case of [2,2′-binaphthalene]-1,1′-dithiolate this represents an infrequent example of a metal complex containing this ligand. All the complexes have been fully characterised using multinuclear NMR spectroscopy and single crystal X-ray diffraction. The single crystal X-ray structure of the starting material [Cp*Rh(PMe3)Br2] ( 1 ) is also reported for the first time. | |
dc.language.iso | eng | |
dc.relation.ispartof | Cogent Chemistry | en |
dc.rights | © 2016 The Authors. This open access article is distributed under a Creative Commons Attribution (CC-BY) 4.0 license. | en |
dc.subject | Dithiolates | en |
dc.subject | Half sandwich | en |
dc.subject | Complexation | en |
dc.subject | Rhodium | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.1080/23312009.2016.1245900 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.tandfonline.com/doi/abs/10.1080/23312009.2016.1245900 | en |
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