Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation
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A series of rhodium(III) half sandwich complexes of the type [Cp*Rh(PMe3)(S—R—S)]; S—R—S = naphthalene-1,8-dithiolate, acenaphthene-5,6-dithiolate, [1,1′-biphenyl]-2,2′-dithiolate and [2,2′-binaphthalene]-1,1′-dithiolate are reported. In the case of [2,2′-binaphthalene]-1,1′-dithiolate this represents an infrequent example of a metal complex containing this ligand. All the complexes have been fully characterised using multinuclear NMR spectroscopy and single crystal X-ray diffraction. The single crystal X-ray structure of the starting material [Cp*Rh(PMe3)Br2] ( 1 ) is also reported for the first time.
Nejman , P S , Slawin , A M Z , Kilian , P & Woollins , J D 2016 , ' Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigation ' Cogent Chemistry , vol. 2 , no. 1 , 1245900 . DOI: 10.1080/23312009.2016.1245900
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