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Structural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexes
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dc.contributor.author | Nejman, Phillip | |
dc.contributor.author | Morton-Fernandez, Brian | |
dc.contributor.author | Moulding, David | |
dc.contributor.author | Athukorala Arachchige, Kasun Sankalpa | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Kilian, Petr | |
dc.contributor.author | Woollins, J Derek | |
dc.date.accessioned | 2016-08-26T23:34:47Z | |
dc.date.available | 2016-08-26T23:34:47Z | |
dc.date.issued | 2015 | |
dc.identifier | 212539424 | |
dc.identifier | a9c88f5d-65f8-44cc-a851-3984577fb9bd | |
dc.identifier | 84942278775 | |
dc.identifier | 000361671000016 | |
dc.identifier.citation | Nejman , P , Morton-Fernandez , B , Moulding , D , Athukorala Arachchige , K S , Cordes , D B , Slawin , A M Z , Kilian , P & Woollins , J D 2015 , ' Structural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexes ' , Dalton Transactions , vol. In press . https://doi.org/10.1039/C5DT02542G | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023997 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861824 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/58285408 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779174 | |
dc.identifier.uri | https://hdl.handle.net/10023/9385 | |
dc.description.abstract | The synthesis of a range of rhodium(III) and iridium(III) half sandwich complexes with aryl dithiolato ligands of varying geometry and flexibility is reported. These include dinuclear [Cp*M(S‒R‒S)]2 complexes 3b and 4b, M = Rh, Ir; S‒R‒S = naphthalene-1,8-dithiolate (b) and four dinuclear complexes bearing bridging dithiolate ligands [(Cp*M)2(μ2-Cl)(μ2-S‒R‒S)]Cl 3c, 4c, 5b, 6b, M = Rh, Ir; S‒R‒S = naphthalene-1,8-dithiolate (b) or acenaphthene-5,6-dithiolate (c). The introduction of a less rigid biphenyl dithiolate backbone resulted in the tetranuclear dicationic complex [(Cp*Rh)4(S-R-S)3]Cl2 (3d), S‒R‒S = biphenyl-2,2’-dithiolate (d) with dithiolate ligands in two different bridging modes. All new complexes were fully characterised by multinuclear NMR, IR, Raman and MS spectroscopy and single crystal X-ray diffraction. | |
dc.format.extent | 790029 | |
dc.format.extent | 357617 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Structural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexes | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1039/C5DT02542G | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-08-26 | |
dc.identifier.url | http://www.rsc.org/suppdata/c5/dt/c5dt02542g/c5dt02542g1.pdf | en |
dc.identifier.url | http://www.rsc.org/suppdata/c5/dt/c5dt02542g/c5dt02542g2.cif | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
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