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dc.contributor.authorNejman, Phillip
dc.contributor.authorMorton-Fernandez, Brian
dc.contributor.authorMoulding, David
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorKilian, Petr
dc.contributor.authorWoollins, J Derek
dc.identifier.citationNejman , P , Morton-Fernandez , B , Moulding , D , Athukorala Arachchige , K S , Cordes , D B , Slawin , A M Z , Kilian , P & Woollins , J D 2015 , ' Structural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexes ' , Dalton Transactions , vol. In press .
dc.identifier.otherPURE: 212539424
dc.identifier.otherPURE UUID: a9c88f5d-65f8-44cc-a851-3984577fb9bd
dc.identifier.otherScopus: 84942278775
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023997
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861824
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285408
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779174
dc.identifier.otherWOS: 000361671000016
dc.description.abstractThe synthesis of a range of rhodium(III) and iridium(III) half sandwich complexes with aryl dithiolato ligands of varying geometry and flexibility is reported. These include dinuclear [Cp*M(S‒R‒S)]2 complexes 3b and 4b, M = Rh, Ir; S‒R‒S = naphthalene-1,8-dithiolate (b) and four dinuclear complexes bearing bridging dithiolate ligands [(Cp*M)2(μ2-Cl)(μ2-S‒R‒S)]Cl 3c, 4c, 5b, 6b, M = Rh, Ir; S‒R‒S = naphthalene-1,8-dithiolate (b) or acenaphthene-5,6-dithiolate (c). The introduction of a less rigid biphenyl dithiolate backbone resulted in the tetranuclear dicationic complex [(Cp*Rh)4(S-R-S)3]Cl2 (3d), S‒R‒S = biphenyl-2,2’-dithiolate (d) with dithiolate ligands in two different bridging modes. All new complexes were fully characterised by multinuclear NMR, IR, Raman and MS spectroscopy and single crystal X-ray diffraction.
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectQD Chemistryen
dc.titleStructural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.description.statusPeer revieweden

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