NMR Studies of Platinum bisphosphine complexes of phenylphosphonamidodiselenoate
Abstract
A series of platinum (II) bisphosphine complexes 1-20 [Pt(R’NH(Ph)PSe2)(PR3)2] (where R = Ph3, Ph2Me, Me2Ph, PMe3 and R’ = iPr, nBu, sBu, tBu, Benz) have been prepared by reaction of cis-[Pt(PR3)2Cl2)] and the alkyl ammonium salt of the ligand. The novel compounds were characterised by multinuclear NMR, and in one case X-Ray crystallography. The molecular structures of two ligand salts and [Pt(sBu’NH(Ph)PSe2)(PPh3)2] are reported.
Citation
Garland , J , Cordes , D B , Slawin , A M Z & Derek Woollins , J 2015 , ' NMR Studies of Platinum bisphosphine complexes of phenylphosphonamidodiselenoate ' , Polyhedron . https://doi.org/10.1016/j.poly.2015.05.008
Publication
Polyhedron
Status
Peer reviewed
ISSN
0277-5387Type
Journal article
Collections
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