NMR Studies of Platinum bisphosphine complexes of phenylphosphonamidodiselenoate
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A series of platinum (II) bisphosphine complexes 1-20 [Pt(R’NH(Ph)PSe2)(PR3)2] (where R = Ph3, Ph2Me, Me2Ph, PMe3 and R’ = iPr, nBu, sBu, tBu, Benz) have been prepared by reaction of cis-[Pt(PR3)2Cl2)] and the alkyl ammonium salt of the ligand. The novel compounds were characterised by multinuclear NMR, and in one case X-Ray crystallography. The molecular structures of two ligand salts and [Pt(sBu’NH(Ph)PSe2)(PPh3)2] are reported.
Garland , J , Cordes , D B , Slawin , A M Z & Derek Woollins , J 2015 , ' NMR Studies of Platinum bisphosphine complexes of phenylphosphonamidodiselenoate ' Polyhedron . DOI: 10.1016/j.poly.2015.05.008
Copyright © 2015 Published by Elsevier Ltd. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1016/j.poly.2015.05.008
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