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Selectively fluorinated cyclohexane building blocks : derivatives of carbonylated all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane

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dc.contributor.authorAyoup, Mohammed Salah
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorO'Hagan, David
dc.date.accessioned2016-04-14T14:00:08Z
dc.date.available2016-04-14T14:00:08Z
dc.date.issued2015-12-21
dc.identifier.citationAyoup , M S , Cordes , D B , Slawin , A M Z & O'Hagan , D 2015 , ' Selectively fluorinated cyclohexane building blocks : derivatives of carbonylated all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane ' , Beilstein Journal of Organic Chemistry , vol. 11 , pp. 2671-2676 . https://doi.org/10.3762/bjoc.11.287en
dc.identifier.issn1860-5397
dc.identifier.otherPURE: 241943679
dc.identifier.otherPURE UUID: 0ba43b62-dabf-462a-9ed6-6a7cfe5c9c50
dc.identifier.otherScopus: 84961859368
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023994
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861786
dc.identifier.otherWOS: 000366964700001
dc.identifier.otherORCID: /0000-0002-0510-5552/work/68281261
dc.identifier.urihttps://hdl.handle.net/10023/8614
dc.descriptionMA thanks the Egyptian Government for a Scholarship under the Channel Scheme and we are grateful to the support of Professor L. Fathey of the University of Alexandria, Department of Chemistry, Egypt. DO'H thanks the Royal Society for a Wolfson Research Merit Award and we also thank the EPSRC Mass Spectrometry Service at Swansea University, UK for analyses.en
dc.description.abstractPalladium catalysed carbonylation reactions using the meta- and para-iodo derivatives of all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane ( 4 ) are illustrated as the start point for a variety of functional group interconversions. The resultant benzaldehyde and benzoic acids offer novel building blocks for further derivatisation and facilitate the incorporation of the facially polarised all-cis-1,2,4,5-tetrafluorocyclohexane motif into more advanced molecular scaffolds.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.rights© 2015 Ayoup et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.en
dc.subjectCyclohexane carbonylationen
dc.subjectFluorine containing building blocks: organofluorine chemistryen
dc.subjectQD Chemistryen
dc.subjectOrganic Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSelectively fluorinated cyclohexane building blocks : derivatives of carbonylated all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexaneen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.identifier.doihttps://doi.org/10.3762/bjoc.11.287
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/F03055X/1en
dc.identifier.grantnumberEP/H022651/1en


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