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On the role of chalcogen donor atoms in diimine-dichalcogenolate PtII SONLO chromophores : is it worth replacing sulfur with selenium?

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dc.contributor.authorPintus, A.
dc.contributor.authorAragoni, M.C.
dc.contributor.authorIsaia, F.
dc.contributor.authorLippolis, V.
dc.contributor.authorLorcy, D.
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorArca, M.
dc.date.accessioned2016-04-01T14:00:04Z
dc.date.available2016-04-01T14:00:04Z
dc.date.issued2015-11
dc.identifier.citationPintus , A , Aragoni , M C , Isaia , F , Lippolis , V , Lorcy , D , Slawin , A M Z , Woollins , J D & Arca , M 2015 , ' On the role of chalcogen donor atoms in diimine-dichalcogenolate Pt II SONLO chromophores : is it worth replacing sulfur with selenium? ' , European Journal of Inorganic Chemistry , vol. 2015 , no. 31 , pp. 5163–5170 . https://doi.org/10.1002/ejic.201500777en
dc.identifier.issn1434-1948
dc.identifier.otherPURE: 222593716
dc.identifier.otherPURE UUID: bb3650ab-9844-4b15-96e9-775f0450be8e
dc.identifier.otherScopus: 84946493714
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861328
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779170
dc.identifier.otherWOS: 000364326900003
dc.identifier.urihttps://hdl.handle.net/10023/8539
dc.description.abstractTwo new diimine-diselenolate PtII chromophores [Pt(bipy)(Me-dset)] (1) and [Pt(phen)(Me-dset)] (2) (Me-dset2- = N-methyl-2-thioxothiazoline-4,5-diselenolate) were synthesized and characterized. The effect of replacing sulfur with selenium was investigated by comparing the UV/Vis spectroscopic and electrochemical properties of 1 and 2 with those of the corresponding sulfur analogues, [Pt(bipy)(Me-dmet)] (3) and [Pt(phen)(Me-dmet)] (4), with a particular focus on their linear and nonlinear optical properties.
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.rightsCopyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/ejic.201500777en
dc.rightsCopyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/ejic.201500777en
dc.subjectSolvatochromismen
dc.subjectDiselenolateen
dc.subjectDiimineen
dc.subjectNonlinear opticsen
dc.subjectDensity functional calculationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleOn the role of chalcogen donor atoms in diimine-dichalcogenolate PtII SONLO chromophores : is it worth replacing sulfur with selenium?en
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.description.versionPostprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1002/ejic.201500777
dc.description.statusPeer revieweden
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/ejic.201500777/suppinfoen
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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