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On the role of chalcogen donor atoms in diimine-dichalcogenolate PtII SONLO chromophores : is it worth replacing sulfur with selenium?
Item metadata
dc.contributor.author | Pintus, A. | |
dc.contributor.author | Aragoni, M.C. | |
dc.contributor.author | Isaia, F. | |
dc.contributor.author | Lippolis, V. | |
dc.contributor.author | Lorcy, D. | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.contributor.author | Arca, M. | |
dc.date.accessioned | 2016-04-01T14:00:04Z | |
dc.date.available | 2016-04-01T14:00:04Z | |
dc.date.issued | 2015-11 | |
dc.identifier | 222593716 | |
dc.identifier | bb3650ab-9844-4b15-96e9-775f0450be8e | |
dc.identifier | 84946493714 | |
dc.identifier | 000364326900003 | |
dc.identifier.citation | Pintus , A , Aragoni , M C , Isaia , F , Lippolis , V , Lorcy , D , Slawin , A M Z , Woollins , J D & Arca , M 2015 , ' On the role of chalcogen donor atoms in diimine-dichalcogenolate Pt II SONLO chromophores : is it worth replacing sulfur with selenium? ' , European Journal of Inorganic Chemistry , vol. 2015 , no. 31 , pp. 5163–5170 . https://doi.org/10.1002/ejic.201500777 | en |
dc.identifier.issn | 1434-1948 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861328 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779170 | |
dc.identifier.uri | https://hdl.handle.net/10023/8539 | |
dc.description.abstract | Two new diimine-diselenolate PtII chromophores [Pt(bipy)(Me-dset)] (1) and [Pt(phen)(Me-dset)] (2) (Me-dset2- = N-methyl-2-thioxothiazoline-4,5-diselenolate) were synthesized and characterized. The effect of replacing sulfur with selenium was investigated by comparing the UV/Vis spectroscopic and electrochemical properties of 1 and 2 with those of the corresponding sulfur analogues, [Pt(bipy)(Me-dmet)] (3) and [Pt(phen)(Me-dmet)] (4), with a particular focus on their linear and nonlinear optical properties. | |
dc.format.extent | 611954 | |
dc.format.extent | 631060 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Inorganic Chemistry | en |
dc.subject | Solvatochromism | en |
dc.subject | Diselenolate | en |
dc.subject | Diimine | en |
dc.subject | Nonlinear optics | en |
dc.subject | Density functional calculations | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | On the role of chalcogen donor atoms in diimine-dichalcogenolate PtII SONLO chromophores : is it worth replacing sulfur with selenium? | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1002/ejic.201500777 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/ejic.201500777/suppinfo | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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