On the role of chalcogen donor atoms in diimine-dichalcogenolate PtII SONLO chromophores : is it worth replacing sulfur with selenium?
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Date
11/2015Author
Grant ID
EP/K031252/1
EP/K039210/1
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Two new diimine-diselenolate PtII chromophores [Pt(bipy)(Me-dset)] (1) and [Pt(phen)(Me-dset)] (2) (Me-dset2- = N-methyl-2-thioxothiazoline-4,5-diselenolate) were synthesized and characterized. The effect of replacing sulfur with selenium was investigated by comparing the UV/Vis spectroscopic and electrochemical properties of 1 and 2 with those of the corresponding sulfur analogues, [Pt(bipy)(Me-dmet)] (3) and [Pt(phen)(Me-dmet)] (4), with a particular focus on their linear and nonlinear optical properties.
Citation
Pintus , A , Aragoni , M C , Isaia , F , Lippolis , V , Lorcy , D , Slawin , A M Z , Woollins , J D & Arca , M 2015 , ' On the role of chalcogen donor atoms in diimine-dichalcogenolate Pt II SONLO chromophores : is it worth replacing sulfur with selenium? ' , European Journal of Inorganic Chemistry , vol. 2015 , no. 31 , pp. 5163–5170 . https://doi.org/10.1002/ejic.201500777
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
ISSN
1434-1948Type
Journal article
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