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The Suzuki-Miyaura reaction performed using a palladium-N-Heterocyclic carbene catalyst and a weak inorganic base

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dc.contributor.authorIzquierdo, Frederic
dc.contributor.authorCorpet, Martin Michel Alfred Eton
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2016-02-18T00:12:40Z
dc.date.available2016-02-18T00:12:40Z
dc.date.issued2015
dc.identifier.citationIzquierdo , F , Corpet , M M A E & Nolan , S P 2015 , ' The Suzuki-Miyaura reaction performed using a palladium-N-Heterocyclic carbene catalyst and a weak inorganic base ' , European Journal of Organic Chemistry , pp. 1920-1924 . https://doi.org/10.1002/ejoc.201500043en
dc.identifier.issn1434-193X
dc.identifier.otherPURE: 167702406
dc.identifier.otherPURE UUID: a2010bd1-e51e-4351-9636-165b8b211b56
dc.identifier.otherWOS: 000351207100008
dc.identifier.otherScopus: 85027927482
dc.identifier.urihttps://hdl.handle.net/10023/8252
dc.descriptionWe gratefully acknowledge the EC for funding through the seventh framework program SYNFLOW, the ERC (Advanced Investigator Award ‘FUNCAT’ to SPN) and the EPSRC. S.P.N. is a Royal Society Wolfson Research Merit Award holder.en
dc.description.abstractN-Heterocyclic carbenes (NHCs) have been shown to be useful ligands for the Suzuki-Miyaura cross-coupling at low catalyst loadings. We now report that the commercially available and air-stable [Pd(IPr)(cin)Cl] pre-catalyst permits the formation of various functionalized biaryls from aryl chlorides and boronic acids (37 examples) under very mild conditions using a mixture of ethanol/water as solvent and an inorganic base.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Organic Chemistryen
dc.rightsCopyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Izquierdo, F., Corpet, M. and Nolan, S. P. (2015), The Suzuki–Miyaura Reaction Performed Using a Palladium–N-Heterocyclic Carb­ene Catalyst and a Weak Inorganic Base. Eur. J. Org. Chem., which has been published in final form at: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201500043/abstracten
dc.subjectCatalysisen
dc.subjectCross-couplingen
dc.subjectNHCen
dc.subjectPalladiumen
dc.subjectSuzuki-Miyauraen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleThe Suzuki-Miyaura reaction performed using a palladium-N-Heterocyclic carbene catalyst and a weak inorganic baseen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.sponsorEuropean Commissionen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/ejoc.201500043
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-02-18
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/ejoc.201500043/suppinfoen
dc.identifier.grantnumberFP7-227817 FUNCATen
dc.identifier.grantnumber246461en


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