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Molecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compounds

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dc.contributor.authorMatuska, Vit
dc.contributor.authorTersago, Karla
dc.contributor.authorKilian, Petr
dc.contributor.authorVan Alsenoy, Christian
dc.contributor.authorBlockhuys, Frank
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2016-01-15T14:40:06Z
dc.date.available2016-01-15T14:40:06Z
dc.date.issued2009-10
dc.identifier4637337
dc.identifier4c1dea9c-fa08-410f-9517-449e94a856ff
dc.identifier000271572100015
dc.identifier70350147806
dc.identifier.citationMatuska , V , Tersago , K , Kilian , P , Van Alsenoy , C , Blockhuys , F , Slawin , A M Z & Woollins , J D 2009 , ' Molecular and crystal structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and related compounds ' , European Journal of Inorganic Chemistry , vol. 2009 , no. 29-30 , pp. 4483-4490 . https://doi.org/10.1002/ejic.200900541en
dc.identifier.issn1434-1948
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862100
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285423
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779269
dc.identifier.urihttps://hdl.handle.net/10023/8025
dc.descriptionThis work is funded by EPSRC UK.en
dc.description.abstractCp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory.
dc.format.extent8
dc.format.extent607919
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.subjectMetallacyclesen
dc.subjectRhodiumen
dc.subjectStructure elucidationen
dc.subjectDensity functional calculationsen
dc.subjectTransition-Metal-Complexesen
dc.subjectNuclear magnetic-resonanceen
dc.subjectSulfur Nitrogen complexesen
dc.subjectAuxiliary basis-setsen
dc.subjectRoeskys Sulfoxideen
dc.subjectLiquid-ammoniaen
dc.subjectReactivityen
dc.subjectCPCOS2N2en
dc.subjectS4N4en
dc.subject1/2PH2PCH2CH2PPH2en
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleMolecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compoundsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1002/ejic.200900541
dc.description.statusPeer revieweden
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/ejic.200900541/suppinfoen


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