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Molecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compounds

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dc.contributor.authorMatuska, Vit
dc.contributor.authorTersago, Karla
dc.contributor.authorKilian, Petr
dc.contributor.authorVan Alsenoy, Christian
dc.contributor.authorBlockhuys, Frank
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2016-01-15T14:40:06Z
dc.date.available2016-01-15T14:40:06Z
dc.date.issued2009-10
dc.identifier.citationMatuska , V , Tersago , K , Kilian , P , Van Alsenoy , C , Blockhuys , F , Slawin , A M Z & Woollins , J D 2009 , ' Molecular and crystal structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and related compounds ' , European Journal of Inorganic Chemistry , vol. 2009 , no. 29-30 , pp. 4483-4490 . https://doi.org/10.1002/ejic.200900541en
dc.identifier.issn1434-1948
dc.identifier.otherPURE: 4637337
dc.identifier.otherPURE UUID: 4c1dea9c-fa08-410f-9517-449e94a856ff
dc.identifier.otherWOS: 000271572100015
dc.identifier.otherScopus: 70350147806
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862100
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285423
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779269
dc.identifier.urihttps://hdl.handle.net/10023/8025
dc.descriptionThis work is funded by EPSRC UK.en
dc.description.abstractCp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory.
dc.format.extent8
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.rightsCopyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/ejic.200900541en
dc.subjectMetallacyclesen
dc.subjectRhodiumen
dc.subjectStructure elucidationen
dc.subjectDensity functional calculationsen
dc.subjectTransition-Metal-Complexesen
dc.subjectNuclear magnetic-resonanceen
dc.subjectSulfur Nitrogen complexesen
dc.subjectAuxiliary basis-setsen
dc.subjectRoeskys Sulfoxideen
dc.subjectLiquid-ammoniaen
dc.subjectReactivityen
dc.subjectCPCOS2N2en
dc.subjectS4N4en
dc.subject1/2PH2PCH2CH2PPH2en
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleMolecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compoundsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1002/ejic.200900541
dc.description.statusPeer revieweden
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/ejic.200900541/suppinfoen


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