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Molecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compounds

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cpxmsn2009vit2.pdf (593.6Kb)
Date
10/2009
Author
Matuska, Vit
Tersago, Karla
Kilian, Petr
Van Alsenoy, Christian
Blockhuys, Frank
Slawin, Alexandra Martha Zoya
Woollins, J Derek
Keywords
Metallacycles
Rhodium
Structure elucidation
Density functional calculations
Transition-Metal-Complexes
Nuclear magnetic-resonance
Sulfur Nitrogen complexes
Auxiliary basis-sets
Roeskys Sulfoxide
Liquid-ammonia
Reactivity
CPCOS2N2
S4N4
1/2PH2PCH2CH2PPH2
QD Chemistry
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Abstract
Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory.
Citation
Matuska , V , Tersago , K , Kilian , P , Van Alsenoy , C , Blockhuys , F , Slawin , A M Z & Woollins , J D 2009 , ' Molecular and crystal structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and related compounds ' , European Journal of Inorganic Chemistry , vol. 2009 , no. 29-30 , pp. 4483-4490 . https://doi.org/10.1002/ejic.200900541
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.1002/ejic.200900541
ISSN
1434-1948
Type
Journal article
Rights
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/ejic.200900541
Description
This work is funded by EPSRC UK.
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  • University of St Andrews Research
URL
http://onlinelibrary.wiley.com/doi/10.1002/ejic.200900541/suppinfo
URI
http://hdl.handle.net/10023/8025

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