Molecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compounds
Abstract
Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory.
Citation
Matuska , V , Tersago , K , Kilian , P , Van Alsenoy , C , Blockhuys , F , Slawin , A M Z & Woollins , J D 2009 , ' Molecular and crystal structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and related compounds ' European Journal of Inorganic Chemistry , vol 2009 , no. 29-30 , pp. 4483-4490 . DOI: 10.1002/ejic.200900541
Version
Postprint
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
URI
http://hdl.handle.net/10023/8025http://onlinelibrary.wiley.com/doi/10.1002/ejic.200900541/suppinfo
ISSN
1434-1948Type
Journal article
Rights
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/ejic.200900541
Description
This work is funded by EPSRC UK.
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