Molecular and crystal structures of Cp*M(S2N2) (M = Co, Rh, Ir) and related compounds
Abstract
Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory.
Citation
Matuska , V , Tersago , K , Kilian , P , Van Alsenoy , C , Blockhuys , F , Slawin , A M Z & Woollins , J D 2009 , ' Molecular and crystal structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and related compounds ' , European Journal of Inorganic Chemistry , vol. 2009 , no. 29-30 , pp. 4483-4490 . https://doi.org/10.1002/ejic.200900541
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
ISSN
1434-1948Type
Journal article
Description
This work is funded by EPSRC UK.Collections
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