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A simple access to transition metal cyclopropenylidene complexes

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dc.contributor.authorBidal, Yannick Daniel
dc.contributor.authorLesieur, Mathieu
dc.contributor.authorMelaimi, Mohand
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBertrand , Guy
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2016-01-15T00:12:03Z
dc.date.available2016-01-15T00:12:03Z
dc.date.issued2015-03-21
dc.identifier171447245
dc.identifiere1cfc9f6-7960-4315-8621-cb42525bcaf8
dc.identifier84924363516
dc.identifier000351056200006
dc.identifier25621852
dc.identifier.citationBidal , Y D , Lesieur , M , Melaimi , M , Cordes , D B , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' A simple access to transition metal cyclopropenylidene complexes ' , Chemical Communications , vol. 51 , no. 23 , pp. 4778-4781 . https://doi.org/10.1039/C4CC10375Ken
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024007
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862114
dc.identifier.urihttps://hdl.handle.net/10023/8019
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.en
dc.description.abstractWe report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.
dc.format.extent893899
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleA simple access to transition metal cyclopropenylidene complexesen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C4CC10375K
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-01-15
dc.identifier.grantnumberUF100691en
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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