A simple access to transition metal cyclopropenylidene complexes
MetadataShow full item record
Altmetrics Handle Statistics
Altmetrics DOI Statistics
We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.
Bidal , Y D , Lesieur , M , Melaimi , M , Cordes , D B , Slawin , A M Z , Bertrand , G & Cazin , C S J 2015 , ' A simple access to transition metal cyclopropenylidene complexes ' , Chemical Communications , vol. 51 , no. 23 , pp. 4778-4781 . https://doi.org/10.1039/C4CC10375K
Copyright the Authors 2015. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://doi.org/10.1039/C4CC10375K
DescriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.