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Conformational preferences of Ac-Gly-NHMe in solution

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dc.contributor.authorCormanich, Rodrigo Antonio
dc.contributor.authorRittner, Roberto
dc.contributor.authorBuehl, Michael
dc.date.accessioned2016-01-13T00:12:08Z
dc.date.available2016-01-13T00:12:08Z
dc.date.issued2015
dc.identifier.citationCormanich , R A , Rittner , R & Buehl , M 2015 , ' Conformational preferences of Ac-Gly-NHMe in solution ' , RSC Advances , vol. 5 , no. 16 , pp. 13052-13060 . https://doi.org/10.1039/C4RA16472Een
dc.identifier.issn2046-2069
dc.identifier.otherPURE: 161860563
dc.identifier.otherPURE UUID: 0cb56d5e-a2a4-4cf4-ac4a-0f1b58e06477
dc.identifier.otherWOS: 000348987700072
dc.identifier.otherScopus: 84961365703
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131806
dc.identifier.urihttps://hdl.handle.net/10023/8010
dc.descriptionThe authors thank a Grant # 2012/03933-5, São Paulo Research Foundation (FAPESP) for providing financial support for this research and a scholarship to RAC #2011/01170-1 (FAPESP). CNPq is also acknowledged, such as for fellowships (to RR) and a studentship (to RAC).en
dc.description.abstractThe conformational behaviour of Ac-Gly-NHMe in nonpolar, polar and polar protic solutions was systematically studied in this work by theoretical calculations and experimental infrared and 1H NMR spectroscopies. Ac-Gly-NHMe prefers a gauche conformer with a strong seven-membered intramolecular hydrogen bond for the isolated compound and in nonpolar solvents, but such preference changes in polar and polar protic solvents. Elucidation of Ac-Gly-NHMe preferences was also supported by studying the conformers of its CF3-C(O)-Gly-NHMe and Ac-Gly-N(Me)2 derivatives in solution.
dc.language.isoeng
dc.relation.ispartofRSC Advancesen
dc.rights© Royal Society of Chemistry 2015. No further copies may be made or distributed. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4RA16472Een
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleConformational preferences of Ac-Gly-NHMe in solutionen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C4RA16472E
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-01-13


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