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dc.contributor.authorCormanich, Rodrigo Antonio
dc.contributor.authorRittner, Roberto
dc.contributor.authorBuehl, Michael
dc.date.accessioned2016-01-13T00:12:08Z
dc.date.available2016-01-13T00:12:08Z
dc.date.issued2015
dc.identifier161860563
dc.identifier0cb56d5e-a2a4-4cf4-ac4a-0f1b58e06477
dc.identifier000348987700072
dc.identifier84961365703
dc.identifier.citationCormanich , R A , Rittner , R & Buehl , M 2015 , ' Conformational preferences of Ac-Gly-NHMe in solution ' , RSC Advances , vol. 5 , no. 16 , pp. 13052-13060 . https://doi.org/10.1039/C4RA16472Een
dc.identifier.issn2046-2069
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131806
dc.identifier.urihttps://hdl.handle.net/10023/8010
dc.descriptionThe authors thank a Grant # 2012/03933-5, São Paulo Research Foundation (FAPESP) for providing financial support for this research and a scholarship to RAC #2011/01170-1 (FAPESP). CNPq is also acknowledged, such as for fellowships (to RR) and a studentship (to RAC).en
dc.description.abstractThe conformational behaviour of Ac-Gly-NHMe in nonpolar, polar and polar protic solutions was systematically studied in this work by theoretical calculations and experimental infrared and 1H NMR spectroscopies. Ac-Gly-NHMe prefers a gauche conformer with a strong seven-membered intramolecular hydrogen bond for the isolated compound and in nonpolar solvents, but such preference changes in polar and polar protic solvents. Elucidation of Ac-Gly-NHMe preferences was also supported by studying the conformers of its CF3-C(O)-Gly-NHMe and Ac-Gly-N(Me)2 derivatives in solution.
dc.format.extent471331
dc.language.isoeng
dc.relation.ispartofRSC Advancesen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleConformational preferences of Ac-Gly-NHMe in solutionen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/C4RA16472E
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-01-13


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