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Conformational preferences of Ac-Gly-NHMe in solution
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dc.contributor.author | Cormanich, Rodrigo Antonio | |
dc.contributor.author | Rittner, Roberto | |
dc.contributor.author | Buehl, Michael | |
dc.date.accessioned | 2016-01-13T00:12:08Z | |
dc.date.available | 2016-01-13T00:12:08Z | |
dc.date.issued | 2015 | |
dc.identifier | 161860563 | |
dc.identifier | 0cb56d5e-a2a4-4cf4-ac4a-0f1b58e06477 | |
dc.identifier | 000348987700072 | |
dc.identifier | 84961365703 | |
dc.identifier.citation | Cormanich , R A , Rittner , R & Buehl , M 2015 , ' Conformational preferences of Ac-Gly-NHMe in solution ' , RSC Advances , vol. 5 , no. 16 , pp. 13052-13060 . https://doi.org/10.1039/C4RA16472E | en |
dc.identifier.issn | 2046-2069 | |
dc.identifier.other | ORCID: /0000-0002-1095-7143/work/48131806 | |
dc.identifier.uri | https://hdl.handle.net/10023/8010 | |
dc.description | The authors thank a Grant # 2012/03933-5, São Paulo Research Foundation (FAPESP) for providing financial support for this research and a scholarship to RAC #2011/01170-1 (FAPESP). CNPq is also acknowledged, such as for fellowships (to RR) and a studentship (to RAC). | en |
dc.description.abstract | The conformational behaviour of Ac-Gly-NHMe in nonpolar, polar and polar protic solutions was systematically studied in this work by theoretical calculations and experimental infrared and 1H NMR spectroscopies. Ac-Gly-NHMe prefers a gauche conformer with a strong seven-membered intramolecular hydrogen bond for the isolated compound and in nonpolar solvents, but such preference changes in polar and polar protic solvents. Elucidation of Ac-Gly-NHMe preferences was also supported by studying the conformers of its CF3-C(O)-Gly-NHMe and Ac-Gly-N(Me)2 derivatives in solution. | |
dc.format.extent | 471331 | |
dc.language.iso | eng | |
dc.relation.ispartof | RSC Advances | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Conformational preferences of Ac-Gly-NHMe in solution | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C4RA16472E | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-01-13 |
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