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Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings
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dc.contributor.author | Nordheider, Andreas | |
dc.contributor.author | Athukorala Arachchige, Kasun Sankalpa | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.contributor.author | Chivers, Tristram | |
dc.date.accessioned | 2015-12-03T00:11:41Z | |
dc.date.available | 2015-12-03T00:11:41Z | |
dc.date.issued | 2015-05-21 | |
dc.identifier | 159870296 | |
dc.identifier | 5eb685e3-bc54-4297-b70a-245c428e5ef9 | |
dc.identifier | 000354203400003 | |
dc.identifier | 84929093628 | |
dc.identifier.citation | Nordheider , A , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' Sodium and rhodium complexes of a spirocyclic Te 5 dianion supported by P 2 N 2 rings ' , Dalton Transactions , vol. 44 , no. 19 , pp. 8781-8783 . https://doi.org/10.1039/C4DT03257H | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861545 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779177 | |
dc.identifier.uri | https://hdl.handle.net/10023/7882 | |
dc.description | The authors thank EPSRC and NSERC (Canada) for financial support. | en |
dc.description.abstract | Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex. | |
dc.format.extent | 697165 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/C4DT03257H | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2015-12-03 | |
dc.identifier.url | http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h1.pdf | en |
dc.identifier.url | http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h2.cif | en |
dc.identifier.grantnumber | EP/K503940/1 | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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