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dc.contributor.authorNordheider, Andreas
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorChivers, Tristram
dc.date.accessioned2015-12-03T00:11:41Z
dc.date.available2015-12-03T00:11:41Z
dc.date.issued2015-05-21
dc.identifier.citationNordheider , A , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' Sodium and rhodium complexes of a spirocyclic Te 5 dianion supported by P 2 N 2 rings ' Dalton Transactions , vol. 44 , no. 19 , pp. 8781-8783 . https://doi.org/10.1039/C4DT03257Hen
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 159870296
dc.identifier.otherPURE UUID: 5eb685e3-bc54-4297-b70a-245c428e5ef9
dc.identifier.otherScopus: 84929093628
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861545
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779177
dc.identifier.otherWOS: 000354203400003
dc.identifier.urihttp://hdl.handle.net/10023/7882
dc.descriptionThe authors thank EPSRC and NSERC (Canada) for financial support.en
dc.description.abstractReactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rights© Royal Society of Chemistry 2015. This work may not be further copied or distributed. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4DT03257Hen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 ringsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C4DT03257H
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-12-03
dc.identifier.urlhttp://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h1.pdfen
dc.identifier.urlhttp://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h2.cifen


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