Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Nordheider, Andreas; Athukorala Arachchige, Kasun Sankalpa; Slawin, Alexandra Martha Zoya; Woollins, J Derek; Chivers, Tristram

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dc.contributor.author	Nordheider, Andreas
dc.contributor.author	Athukorala Arachchige, Kasun Sankalpa
dc.contributor.author	Slawin, Alexandra Martha Zoya
dc.contributor.author	Woollins, J Derek
dc.contributor.author	Chivers, Tristram
dc.date.accessioned	2015-12-03T00:11:41Z
dc.date.available	2015-12-03T00:11:41Z
dc.date.issued	2015-05-21
dc.identifier.citation	Nordheider , A , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' Sodium and rhodium complexes of a spirocyclic Te 5 dianion supported by P 2 N 2 rings ' , Dalton Transactions , vol. 44 , no. 19 , pp. 8781-8783 . https://doi.org/10.1039/C4DT03257H	en
dc.identifier.issn	1477-9226
dc.identifier.other	PURE: 159870296
dc.identifier.other	PURE UUID: 5eb685e3-bc54-4297-b70a-245c428e5ef9
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/56861545
dc.identifier.other	ORCID: /0000-0002-1498-9652/work/31779177
dc.identifier.other	WOS: 000354203400003
dc.identifier.other	Scopus: 84929093628
dc.identifier.uri	https://hdl.handle.net/10023/7882
dc.description	The authors thank EPSRC and NSERC (Canada) for financial support.	en
dc.description.abstract	Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [CpRhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the CpRh complex.
dc.language.iso	eng
dc.relation.ispartof	Dalton Transactions	en
dc.rights	© Royal Society of Chemistry 2015. This work may not be further copied or distributed. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4DT03257H	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject.lcc	QD	en
dc.title	Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings	en
dc.type	Journal article	en
dc.contributor.sponsor	EPSRC	en
dc.contributor.sponsor	EPSRC	en
dc.contributor.sponsor	EPSRC	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. Office of the Principal	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1039/C4DT03257H
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2015-12-03
dc.identifier.url	http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h1.pdf	en
dc.identifier.url	http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h2.cif	en
dc.identifier.grantnumber	EP/K503940/1	en
dc.identifier.grantnumber	EP/K031252/1	en
dc.identifier.grantnumber	EP/K039210/1	en

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