Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings
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Date
21/05/2015Author
Grant ID
EP/K503940/1
EP/K031252/1
EP/K039210/1
Metadata
Show full item recordAbstract
Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.
Citation
Nordheider , A , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' Sodium and rhodium complexes of a spirocyclic Te 5 dianion supported by P 2 N 2 rings ' , Dalton Transactions , vol. 44 , no. 19 , pp. 8781-8783 . https://doi.org/10.1039/C4DT03257H
Publication
Dalton Transactions
Status
Peer reviewed
ISSN
1477-9226Type
Journal article
Description
The authors thank EPSRC and NSERC (Canada) for financial support.Collections
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