Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings
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Date
21/05/2015Author
Grant ID
EP/K503940/1
EP/K031252/1
EP/K039210/1
Metadata
Show full item recordAbstract
Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.
Citation
Nordheider , A , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' Sodium and rhodium complexes of a spirocyclic Te 5 dianion supported by P 2 N 2 rings ' , Dalton Transactions , vol. 44 , no. 19 , pp. 8781-8783 . https://doi.org/10.1039/C4DT03257H
Publication
Dalton Transactions
Status
Peer reviewed
ISSN
1477-9226Type
Journal article
Rights
© Royal Society of Chemistry 2015. This work may not be further copied or distributed. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4DT03257H
Description
The authors thank EPSRC and NSERC (Canada) for financial support.Collections
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