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dc.contributor.authorSantoro, Orlando
dc.contributor.authorLazreg, Faima
dc.contributor.authorMinenkov, Yury
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S.J.
dc.identifier.citationSantoro , O , Lazreg , F , Minenkov , Y , Cavallo , L & Cazin , C S J 2015 , ' N -Heterocyclic carbene copper(I) catalysed N -methylation of amines using CO 2 ' , Dalton Transactions , vol. 44 , no. 41 , pp. 18138-18144 .
dc.identifier.otherPURE: 220011533
dc.identifier.otherPURE UUID: bcfbac51-0555-4be0-9456-b8d80fd11adc
dc.identifier.otherScopus: 84944214411
dc.identifier.otherWOS: 000362792600028
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the EPSRC (DTG011 EP/J500549/1) and the King Abdullah University of Science and Technology for funding, and the EPSRC National Mass Spectrometry Service Centre at Swansea University for HMRS analyses.en
dc.description.abstractThe N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(I) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright 2015 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (
dc.subjectQD Chemistryen
dc.titleN-Heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2en
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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