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dc.contributor.authorAitken, Kati Marianne
dc.contributor.authorAitken, R Alan
dc.contributor.authorMacGregor, Callum I.
dc.contributor.authorTraore, Mohamed D. M.
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.date.accessioned2015-11-17T12:10:02Z
dc.date.available2015-11-17T12:10:02Z
dc.date.issued2015-12
dc.identifier.citationAitken , K M , Aitken , R A , MacGregor , C I , Traore , M D M & Slawin , A M Z 2015 , ' The X-ray Structures of 2,4-Dibromothiazole and 2,4-diacetyl-5-bromothiazole ' , Journal of Chemical Crystallography , vol. 45 , no. 10-12 , pp. 461-465 . https://doi.org/10.1007/s10870-015-0615-xen
dc.identifier.issn1074-1542
dc.identifier.otherPURE: 228053896
dc.identifier.otherPURE UUID: 84b4386e-a781-495b-8351-f9c504c47d51
dc.identifier.otherScopus: 84947939935
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857575
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861406
dc.identifier.otherWOS: 000365444500005
dc.identifier.urihttp://hdl.handle.net/10023/7802
dc.description.abstract2,4-Dibromothiazole [orthorhombic, a = 6.700(10), b = 16.21(3), c = 5.516(8) Å, space group Fmm2] shows a disordered crystal structure with molecules randomly oriented with respect to the direction of the Br–C(2)–N–C(2)–Br unit and the remaining ring atoms S(3) and C(3)H showing mixed occupancy. 2,4-Diacetyl-5-bromothiazole [triclinic, a = 4.040(2), b = 8.254(5), c = 13.208(8) Å, α = 96.191(17), β = 93.865(16), γ = 94.067(11) °, space group P-1] shows a structure dominated by halogen bonding, intramolecular between 4-COMe and 5-Br and intermolecular between 2-COMe of one molecule and 5-Br of the next.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofJournal of Chemical Crystallographyen
dc.rights© The Author(s) 2015. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://​creativecommons.​org/​licenses/​by/​4.​0/​), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.en
dc.subjectThaizoleen
dc.subjectBromothiazoleen
dc.subjectDisorderen
dc.subjectHalogen bondingen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleThe X-ray Structures of 2,4-Dibromothiazole and 2,4-diacetyl-5-bromothiazoleen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1007/s10870-015-0615-x
dc.description.statusPeer revieweden


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