The X-ray Structures of 2,4-Dibromothiazole and 2,4-diacetyl-5-bromothiazole
MetadataShow full item record
Altmetrics Handle Statistics
Altmetrics DOI Statistics
2,4-Dibromothiazole [orthorhombic, a = 6.700(10), b = 16.21(3), c = 5.516(8) Å, space group Fmm2] shows a disordered crystal structure with molecules randomly oriented with respect to the direction of the Br–C(2)–N–C(2)–Br unit and the remaining ring atoms S(3) and C(3)H showing mixed occupancy. 2,4-Diacetyl-5-bromothiazole [triclinic, a = 4.040(2), b = 8.254(5), c = 13.208(8) Å, α = 96.191(17), β = 93.865(16), γ = 94.067(11) °, space group P-1] shows a structure dominated by halogen bonding, intramolecular between 4-COMe and 5-Br and intermolecular between 2-COMe of one molecule and 5-Br of the next.
Aitken , K M , Aitken , R A , MacGregor , C I , Traore , M D M & Slawin , A M Z 2015 , ' The X-ray Structures of 2,4-Dibromothiazole and 2,4-diacetyl-5-bromothiazole ' , Journal of Chemical Crystallography , vol. 45 , no. 10-12 , pp. 461-465 . https://doi.org/10.1007/s10870-015-0615-x
Journal of Chemical Crystallography
© The Author(s) 2015. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.