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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

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dc.contributor.authorTruscott, Byron
dc.contributor.authorNahra, Fady
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorCordes, David Bradford
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2015-10-27T00:11:37Z
dc.date.available2015-10-27T00:11:37Z
dc.date.issued2015-01-04
dc.identifier159994032
dc.identifier122c2bed-8923-4625-8e96-e03156168ebd
dc.identifier000345909400007
dc.identifier84915750781
dc.identifier.citationTruscott , B , Nahra , F , Slawin , A M Z , Cordes , D B & Nolan , S P 2015 , ' Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I) ' , Chemical Communications , vol. 51 , no. 1 , pp. 62-65 . https://doi.org/10.1039/c4cc07772een
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024020
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862085
dc.identifier.urihttps://hdl.handle.net/10023/7694
dc.descriptionThe ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support.en
dc.description.abstractHerein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.
dc.format.extent4
dc.format.extent771656
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleFluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)en
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/c4cc07772e
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-10-27
dc.identifier.urlhttp://www.rsc.org/suppdata/cc/c4/c4cc07772e/c4cc07772e1.pdfen
dc.identifier.grantnumberFP7-227817 FUNCATen
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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