Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)
View/ Open
Date
04/01/2015Author
Grant ID
FP7-227817 FUNCAT
EP/K031252/1
EP/K039210/1
Metadata
Show full item recordAbstract
Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.
Citation
Truscott , B , Nahra , F , Slawin , A M Z , Cordes , D B & Nolan , S P 2015 , ' Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I) ' , Chemical Communications , vol. 51 , no. 1 , pp. 62-65 . https://doi.org/10.1039/c4cc07772e
Publication
Chemical Communications
Status
Peer reviewed
ISSN
1359-7345Type
Journal article
Rights
Copyright 2014 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/c4cc07772e
Description
The ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support.Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.