Catalyst design in oxidation chemistry; from KMnO4 to artificial metalloenzymes
Abstract
Oxidation reactions are an important part of the synthetic organic chemist’s toolkit and continued advancements have, in many cases, resulted in high yields and selectivities. This review aims to give an overview of the current state-of-the-art in oxygenation reactions using both chemical and enzymatic processes, the design principles applied to date and a possible future in the direction of hybrid catalysts combining the best of chemical and natural design.
Citation
Doble , M , Ward , A C C , Deuss , P , Jarvis , A & Kamer , P C J 2014 , ' Catalyst design in oxidation chemistry; from KMnO 4 to artificial metalloenzymes ' , Bioorganic & Medicinal Chemistry , vol. 22 , no. 20 , pp. 5657-5677 . https://doi.org/10.1016/j.bmc.2014.07.002
Publication
Bioorganic & Medicinal Chemistry
Status
Peer reviewed
ISSN
0968-0896Type
Journal article
Rights
© 2014. Elsevier Inc. All rights reserved. This is the author’s version of a work that was accepted for publication in Bioorganic & Medicinal Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Bioorganic and Medicinal Chemistry, 22, 20, 2014 DOI 10.1016/j.bmc.2014.07.002
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