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Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp3)-H bonds

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dc.contributor.authorFernandez Salas, Jose Antonio
dc.contributor.authorMarelli, Enrico
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2015-07-22T08:40:04Z
dc.date.available2015-07-22T08:40:04Z
dc.date.issued2015-08-01
dc.identifier.citationFernandez Salas , J A , Marelli , E & Nolan , S P 2015 , ' Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp 3 )-H bonds ' , Journal of Polymer Science Part A: Polymer Chemistry , vol. 6 , no. 8 , pp. 4973-4977 . https://doi.org/10.1039/C5SC01589Hen
dc.identifier.issn0887-624X
dc.identifier.otherPURE: 204333631
dc.identifier.otherPURE UUID: e5876da8-388b-4336-98b5-3d6f40717de8
dc.identifier.otherBibtex: urn:3cde3db584f67c593669c88edd6941f3
dc.identifier.otherScopus: 84937239249
dc.identifier.otherWOS: 000357931700072
dc.identifier.urihttps://hdl.handle.net/10023/7008
dc.descriptionThe authors thank the ERC (Advanced Researcher award-FUNCAT), the EPSRC (grant no EP/J011053/1) and King Saud University for funding. SPN is a Royal Society Wolfson Research Merit Award holder.en
dc.description.abstractThe first nickel catalyzed deprotonative cross coupling between C(sp3)-H bonds and aryl chlorides is reported, allowing the challenging arylation of benzylimines in the absence of directing group or stoichiometric metal activation. This methodology represents a convenient access to the (diarylmethyl)amine moiety, which is widespread in pharmaceutically relevant compounds.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofJournal of Polymer Science Part A: Polymer Chemistryen
dc.rightsCopyright 2015 the Authors. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence (http://creativecommons.org/licenses/by-nc/3.0/).en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleSynthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp3)-H bondsen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5SC01589H
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/sc/c5sc01589h/c5sc01589h1.pdfen
dc.identifier.grantnumberFP7-227817 FUNCATen
dc.identifier.grantnumberEP/J011053/1en


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