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dc.contributor.authorRawson, J.M.
dc.contributor.authorDonato, L.
dc.contributor.authorZysman-Colman, E.
dc.date.accessioned2015-07-21T23:10:53Z
dc.date.available2015-07-21T23:10:53Z
dc.date.issued2014-09-28
dc.identifier158992549
dc.identifier92bd2981-48fa-486b-99a6-76780936a9b4
dc.identifier84906232131
dc.identifier000344451800021
dc.identifier.citationRawson , J M , Donato , L & Zysman-Colman , E 2014 , ' Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes ' , CrystEngComm , vol. 16 , no. 36 , pp. 8531-8536 . https://doi.org/10.1039/c4ce00980ken
dc.identifier.issn1466-8033
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639094
dc.identifier.urihttps://hdl.handle.net/10023/7007
dc.description.abstractDespite the differing size of the Cl− and PF6− counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)2(btl)]Cl, [1]Cl, and [Ir(dFphtl)2(btl)]PF6, [1]PF6, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.
dc.format.extent6
dc.format.extent764147
dc.language.isoeng
dc.relation.ispartofCrystEngCommen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleTriazole-directed hydrogen-bonded structures of cationic iridium(III) complexesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/c4ce00980k
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-07-22
dc.identifier.urlhttp://www.rsc.org/suppdata/ce/c4/c4ce00980k/c4ce00980k1.cifen


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