St Andrews Research Repository

St Andrews University Home
View Item 
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  • Register / Login
JavaScript is disabled for your browser. Some features of this site may not work without it.

Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes

Thumbnail
View/Open
revised_ms.pdf (746.2Kb)
Date
28/09/2014
Author
Rawson, J.M.
Donato, L.
Zysman-Colman, E.
Keywords
QD Chemistry
Metadata
Show full item record
Abstract
Despite the differing size of the Cl− and PF6− counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)2(btl)]Cl, [1]Cl, and [Ir(dFphtl)2(btl)]PF6, [1]PF6, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.
Citation
Rawson , J M , Donato , L & Zysman-Colman , E 2014 , ' Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes ' , CrystEngComm , vol. 16 , no. 36 , pp. 8531-8536 . https://doi.org/10.1039/c4ce00980k
Publication
CrystEngComm
Status
Peer reviewed
DOI
https://doi.org/10.1039/c4ce00980k
ISSN
1466-8033
Type
Journal article
Rights
© Royal Society of Chemistry 2014. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4CE00980K
Collections
  • University of St Andrews Research
URL
http://www.rsc.org/suppdata/ce/c4/c4ce00980k/c4ce00980k1.cif
URI
http://hdl.handle.net/10023/7007

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.

Advanced Search

Browse

All of RepositoryCommunities & CollectionsBy Issue DateNamesTitlesSubjectsClassificationTypeFunderThis CollectionBy Issue DateNamesTitlesSubjectsClassificationTypeFunder

My Account

Login

Open Access

To find out how you can benefit from open access to research, see our library web pages and Open Access blog. For open access help contact: openaccess@st-andrews.ac.uk.

Accessibility

Read our Accessibility statement.

How to submit research papers

The full text of research papers can be submitted to the repository via Pure, the University's research information system. For help see our guide: How to deposit in Pure.

Electronic thesis deposit

Help with deposit.

Repository help

For repository help contact: Digital-Repository@st-andrews.ac.uk.

Give Feedback

Cookie policy

This site may use cookies. Please see Terms and Conditions.

Usage statistics

COUNTER-compliant statistics on downloads from the repository are available from the IRUS-UK Service. Contact us for information.

© University of St Andrews Library

University of St Andrews is a charity registered in Scotland, No SC013532.

  • Facebook
  • Twitter