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Rapid asymmetric transfer hydroformylation (ATHF) of disubstituted alkenes using paraformaldehyde as a syngas surrogate
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dc.contributor.author | Fuentes García, José Antonio | |
dc.contributor.author | Pittaway, Rachael | |
dc.contributor.author | Clarke, Matt | |
dc.date.accessioned | 2015-07-08T16:10:10Z | |
dc.date.available | 2015-07-08T16:10:10Z | |
dc.date.issued | 2015-07-14 | |
dc.identifier | 192606476 | |
dc.identifier | cf330912-f31a-4591-87f4-0fbcf992cdcc | |
dc.identifier | 84936990203 | |
dc.identifier | 000357984900007 | |
dc.identifier.citation | Fuentes García , J A , Pittaway , R & Clarke , M 2015 , ' Rapid asymmetric transfer hydroformylation (ATHF) of disubstituted alkenes using paraformaldehyde as a syngas surrogate ' , Chemistry - A European Journal , vol. 21 , no. 30 , pp. 10645-10649 . https://doi.org/10.1002/chem.201502049 | en |
dc.identifier.issn | 0947-6539 | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464621 | |
dc.identifier.uri | https://hdl.handle.net/10023/6939 | |
dc.description | The authors thank Dr. Reddys (UK) and the Royal Society for an Industry Fellowship in the early stage of this work (2012–2014), and the EPSRC for funding (EP/M003868/1). | en |
dc.description.abstract | As an alternative to conventional asymmetric hydroformylation (AHF), Asymmetric Transfer Hydroformylation (ATHF) using formaldehyde as a surrogate for syngas is reported. A catalyst derived from commercially available [Rh(acac)(CO)2] and Ph-BPE stands out in terms of both activity and enantioselectivity. Remarkably, not only are high selectivities achievable, the reactions are very simple to carry out, and can give higher enantioselectivity (up to 96% e.e.) and/or turnover frequencies than those that are achievable using the same catalyst (or other leading catalysts) using typical conditions for AHF. | |
dc.format.extent | 295228 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemistry - A European Journal | en |
dc.subject | Enantioselective Catalysis | en |
dc.subject | Microwave | en |
dc.subject | Carbinylation | en |
dc.subject | Hydroformylation | en |
dc.subject | Formaldehyde | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject | BDC | en |
dc.subject.lcc | QD | en |
dc.title | Rapid asymmetric transfer hydroformylation (ATHF) of disubstituted alkenes using paraformaldehyde as a syngas surrogate | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/chem.201502049 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | IF120023 | en |
dc.identifier.grantnumber | EP/M003868/1 | en |
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