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Hydrogenation of unactivated enamines to tertiary amines : rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity
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dc.contributor.author | Tin, Sergey | |
dc.contributor.author | Fanjul, Tamara | |
dc.contributor.author | Clarke, Matthew L. | |
dc.date.accessioned | 2015-05-26T09:40:03Z | |
dc.date.available | 2015-05-26T09:40:03Z | |
dc.date.issued | 2015-05-05 | |
dc.identifier | 190540421 | |
dc.identifier | 801740c1-622f-4b44-96a1-51905d1a5c01 | |
dc.identifier | 000353874800001 | |
dc.identifier | 84930626192 | |
dc.identifier | 000353874800001 | |
dc.identifier.citation | Tin , S , Fanjul , T & Clarke , M L 2015 , ' Hydrogenation of unactivated enamines to tertiary amines : rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity ' , Beilstein Journal of Organic Chemistry , vol. 11 , pp. 622-627 . https://doi.org/10.3762/bjoc.11.70 | en |
dc.identifier.issn | 1860-5397 | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464598 | |
dc.identifier.uri | https://hdl.handle.net/10023/6693 | |
dc.description | Date of Acceptance: 16/04/2015 | en |
dc.description.abstract | In the hydrogenation of sluggish unactivated enamine substrates, Rh complexes of electron-deficient phosphines are demonstrated to be far more reactive catalysts than those derived from triphenylphosphine. These operate at low catalyst loadings (down to 0.01 mol %) and are able to reduce tetrasubstituted enamines. The use of the sustainable and environmentally benign solvent (R)-limonene for the reaction is also reported with the amine isolated by acid extraction. | |
dc.format.extent | 6 | |
dc.format.extent | 286685 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | Alkenes | en |
dc.subject | Homogeneous catalysis | en |
dc.subject | Hydrogenation | en |
dc.subject | Renewable solvents | en |
dc.subject | Tertiary amines | en |
dc.subject | Asymmetric hydrogenation | en |
dc.subject | Enantioselective synthesis | en |
dc.subject | Functionalized enamines | en |
dc.subject | Hydroformylation | en |
dc.subject | Chemistry | en |
dc.subject | Aldehydes | en |
dc.subject | Ligands | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject | SDG 7 - Affordable and Clean Energy | en |
dc.subject.lcc | QD | en |
dc.title | Hydrogenation of unactivated enamines to tertiary amines : rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.3762/bjoc.11.70 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.beilstein-journals.org/bjoc/single/downloadSuppInfo.htm?publicId=1860-5397-11-70 | en |
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