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A Clean and Selective Radical Homocoupling Employing Carboxylic Acids with Titania Photoredox Catalysis
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dc.contributor.author | Manley, David W. | |
dc.contributor.author | Walton, John C. | |
dc.date.accessioned | 2015-03-17T13:01:01Z | |
dc.date.available | 2015-03-17T13:01:01Z | |
dc.date.issued | 2014-10-17 | |
dc.identifier | 157937449 | |
dc.identifier | 571a5db6-55be-4b26-ac48-622ed414acb0 | |
dc.identifier | 000343526200043 | |
dc.identifier | 84908062867 | |
dc.identifier | 000343526200043 | |
dc.identifier.citation | Manley , D W & Walton , J C 2014 , ' A Clean and Selective Radical Homocoupling Employing Carboxylic Acids with Titania Photoredox Catalysis ' , Organic Letters , vol. 16 , no. 20 , pp. 5394-5397 . https://doi.org/10.1021/ol502625w | en |
dc.identifier.issn | 1523-7060 | |
dc.identifier.other | ORCID: /0000-0003-2746-6276/work/56638664 | |
dc.identifier.uri | https://hdl.handle.net/10023/6254 | |
dc.description.abstract | A titania photoredox catalysis protocol was developed for the homocoupling of C-centered radicals derived from carboxylic acids. Intermolecular reactions were generally efficient and selective, furnishing the desired dimers in good yields under mild neutral conditions. Selective cross-coupling with two acids proved unsuccessful. An intramolecular adaptation enabled macrocycles to be prepared, albeit in modest yields. | |
dc.format.extent | 4 | |
dc.format.extent | 686628 | |
dc.language.iso | eng | |
dc.relation.ispartof | Organic Letters | en |
dc.subject | Coupling-reactions | en |
dc.subject | Organic-synthesis | en |
dc.subject | Natural-products | en |
dc.subject | Tertiary-amines | en |
dc.subject | Polymerizations | en |
dc.subject | Photocatalysis | en |
dc.subject | Alkylations | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | A Clean and Selective Radical Homocoupling Employing Carboxylic Acids with Titania Photoredox Catalysis | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1021/ol502625w | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/I003479/1 | en |
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