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Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

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dc.contributor.authorAitken, R Alan
dc.contributor.authorOyewale, Adebayo O
dc.date.accessioned2015-02-24T15:01:00Z
dc.date.available2015-02-24T15:01:00Z
dc.date.issued2015-02-17
dc.identifier.citationAitken , R A & Oyewale , A O 2015 , ' Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes ' , RSC Advances , vol. 5 , no. 25 , pp. 19379-19381 . https://doi.org/10.1039/C4RA15004Jen
dc.identifier.issn2046-2069
dc.identifier.otherPURE: 161545351
dc.identifier.otherPURE UUID: 017e6bac-b5b6-4578-9291-765308fd6b86
dc.identifier.otherScopus: 84923323495
dc.identifier.otherWOS: 000350043600051
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857580
dc.identifier.urihttps://hdl.handle.net/10023/6139
dc.description.abstractA range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.
dc.format.extent3
dc.language.isoeng
dc.relation.ispartofRSC Advancesen
dc.rights© 2015. The Royal Society of Chemistry. Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleUnexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C4RA15004J
dc.description.statusPeer revieweden


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