Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

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17/02/2015
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Abstract
A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.
Citation
Aitken , R A & Oyewale , A O 2015 , ' Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes ' , RSC Advances , vol. 5 , no. 25 , pp. 19379-19381 . https://doi.org/10.1039/C4RA15004J
Publication
RSC Advances
Status
Peer reviewed
DOI
https://doi.org/10.1039/C4RA15004J
ISSN
2046-2069
Type
Journal article
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© 2015. The Royal Society of Chemistry. Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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http://hdl.handle.net/10023/6139

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