Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes
MetadataShow full item record
Altmetrics Handle Statistics
Altmetrics DOI Statistics
A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.
Aitken , R A & Oyewale , A O 2015 , ' Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes ' , RSC Advances , vol. 5 , no. 25 , pp. 19379-19381 . https://doi.org/10.1039/C4RA15004J
© 2015. The Royal Society of Chemistry. Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.