A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

Aidoudi, Farida H.; Downie, Lewis J.; Morris, Russell E.; de Vries, Mark A.; Lightfoot, Philip

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dc.contributor.author	Aidoudi, Farida H.
dc.contributor.author	Downie, Lewis J.
dc.contributor.author	Morris, Russell E.
dc.contributor.author	de Vries, Mark A.
dc.contributor.author	Lightfoot, Philip
dc.date.accessioned	2015-02-13T00:01:45Z
dc.date.available	2015-02-13T00:01:45Z
dc.date.issued	2014
dc.identifier	128452411
dc.identifier	97278889-28ab-4cbd-9c8e-44e7103adad4
dc.identifier	000333580600006
dc.identifier	84897493291
dc.identifier	000333580600006
dc.identifier.citation	Aidoudi , F H , Downie , L J , Morris , R E , de Vries , M A & Lightfoot , P 2014 , ' A hybrid vanadium fluoride with structurally isolated S=1 kagome layers ' , Dalton Transactions , vol. 43 , no. 17 , pp. 6304-6307 . https://doi.org/10.1039/c4dt00452c	en
dc.identifier.issn	1477-9226
dc.identifier.other	ORCID: /0000-0001-7048-3982/work/59464430
dc.identifier.other	ORCID: /0000-0001-7809-0315/work/61622089
dc.identifier.uri	https://hdl.handle.net/10023/6093
dc.description	Funding: EPSRC Doctoral Prize Fellowship (FHA), Royal Society (REM), US Department of Energy contract no. E-AC02-05CH11231 (ALS).	en
dc.description.abstract	A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.
dc.format.extent	4
dc.format.extent	1723858
dc.language.iso	eng
dc.relation.ispartof	Dalton Transactions	en
dc.subject	Magnetic-properties	en
dc.subject	Oxyfluorides	en
dc.subject	Lattice	en
dc.subject	Temperature	en
dc.subject	Compound	en
dc.subject	QD Chemistry	en
dc.subject.lcc	QD	en
dc.title	A hybrid vanadium fluoride with structurally isolated S=1 kagome layers	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	10.1039/c4dt00452c
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2015-02-13

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