Show simple item record

Files in this item

Thumbnail
Name:
Woollins_2014_ChemComm_TheActivation_CC.pdf
Size:
1.042Mb
Format:
PDF
View/Open

The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2

Item metadata

dc.contributor.authorAscherl, Laura
dc.contributor.authorNordheider, Andreas
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorCordes, David Bradford
dc.contributor.authorKaraghiosoff, Konstantin
dc.contributor.authorBuehl, Michael
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2015-02-10T11:01:01Z
dc.date.available2015-02-10T11:01:01Z
dc.date.issued2014-06-14
dc.identifier138067174
dc.identifier1e78de4c-32ab-47dd-8808-31cee849e6a7
dc.identifier000336793100007
dc.identifier84901022815
dc.identifier000336793100007
dc.identifier.citationAscherl , L , Nordheider , A , Athukorala Arachchige , K S , Cordes , D B , Karaghiosoff , K , Buehl , M , Slawin , A M Z & Woollins , J D 2014 , ' The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe 2 ' , Chemical Communications , vol. 50 , no. 47 , pp. 6214-6216 . https://doi.org/10.1039/c4cc01073fen
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131830
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024027
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861822
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779194
dc.identifier.urihttps://hdl.handle.net/10023/6081
dc.descriptionThe authors are thankful to the School of Chemistry and EaStCHEM for support.en
dc.description.abstractWoollins' reagent (WR, (PhPSe2)2) plays an essential role in the selenation of organic compounds. Reaction of WR with pyridine gives the P(V) species PhPSe2 stabilised by pyridine coordination which is the first crystallographically characterised mononuclear RPSe2 system stabilised by an external molecule and has potential as a selenation reagent for reactions under mild conditions.
dc.format.extent3
dc.format.extent1093370
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectX-rayen
dc.subjectLawessons reagenten
dc.subjectCrystal-structuresen
dc.subjectHeterocyclesen
dc.subjectReactivityen
dc.subjectSelenationen
dc.subjectQD Chemistryen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleThe activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1039/c4cc01073f
dc.description.statusPeer revieweden


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.