The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2

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14/06/2014
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Abstract
Woollins' reagent (WR, (PhPSe2)2) plays an essential role in the selenation of organic compounds. Reaction of WR with pyridine gives the P(V) species PhPSe2 stabilised by pyridine coordination which is the first crystallographically characterised mononuclear RPSe2 system stabilised by an external molecule and has potential as a selenation reagent for reactions under mild conditions.
Citation
Ascherl , L , Nordheider , A , Athukorala Arachchige , K S , Cordes , D B , Karaghiosoff , K , Buehl , M , Slawin , A M Z & Woollins , J D 2014 , ' The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe 2 ' Chemical Communications , vol. 50 , no. 47 , pp. 6214-6216 . DOI: 10.1039/c4cc01073f
Publication
Chemical Communications
Status
Peer reviewed
DOI
https://doi.org/10.1039/c4cc01073f
ISSN
1359-7345
Type
Journal article
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© The Authors 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/)
Description
Date of Acceptance: 22/04/2014
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URI
http://hdl.handle.net/10023/6081

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