The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2
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Woollins' reagent (WR, (PhPSe2)2) plays an essential role in the selenation of organic compounds. Reaction of WR with pyridine gives the P(V) species PhPSe2 stabilised by pyridine coordination which is the first crystallographically characterised mononuclear RPSe2 system stabilised by an external molecule and has potential as a selenation reagent for reactions under mild conditions.
Ascherl , L , Nordheider , A , Athukorala Arachchige , K S , Cordes , D B , Karaghiosoff , K , Buehl , M , Slawin , A M Z & Woollins , J D 2014 , ' The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe 2 ' Chemical Communications , vol. 50 , no. 47 , pp. 6214-6216 . https://doi.org/10.1039/c4cc01073f
© 2014 Royal Society of Chemistry. This is an Accepted Manuscript of an article published in Chemical Communications on 14 June 2014, available online: http://pubs.rsc.org/en/content/articlepdf/2014/cc/c4cc01073f© The Authors 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/)
DescriptionDate of Acceptance: 22/04/2014
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