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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

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dc.contributor.authorAckermann, Katrin
dc.contributor.authorGiannoulis, Angeliki
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBode, Bela Ernest
dc.date.accessioned2015-02-04T09:31:15Z
dc.date.available2015-02-04T09:31:15Z
dc.date.issued2015-03-28
dc.identifier161439545
dc.identifierb9c6cc2e-c420-47af-b69e-f17847e7481b
dc.identifier84925061590
dc.identifier000351393600011
dc.identifier25587579
dc.identifier.citationAckermann , K , Giannoulis , A , Cordes , D B , Slawin , A M Z & Bode , B E 2015 , ' Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR ' , Chemical Communications , vol. 51 , no. 25 , pp. 5257-5260 . https://doi.org/10.1039/C4CC08656Ben
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024018
dc.identifier.otherORCID: /0000-0002-3384-271X/work/36590462
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862023
dc.identifier.urihttps://hdl.handle.net/10023/6067
dc.descriptionAG acknowledges a postgraduate fellowship by the EPSRC funded doctoral training centre ‘integrated magnetic resonance’. BEB is grateful for an EaStCHEM Hirst Academic Fellowship by the School of Chemistry, St Andrews, and funding from the People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programme (REA 334496).en
dc.description.abstractPulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.
dc.format.extent4
dc.format.extent1670883
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleAssessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPRen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Commissionen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Centre of Magnetic Resonanceen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/C4CC08656B
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/cc/c4/c4cc08656b/c4cc08656b1.pdfen
dc.identifier.urlhttp://www.rsc.org/suppdata/cc/c4/c4cc08656b/c4cc08656b2.cifen
dc.identifier.grantnumberen
dc.identifier.grantnumberEP/D061768/1en
dc.identifier.grantnumberEP/K039210/1en


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