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A cooperative Pd-Cu system for direct C-H bond arylation
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dc.contributor.author | Lesieur, Mathieu | |
dc.contributor.author | Lazreg, Faima | |
dc.contributor.author | Cazin, Catherine S. J. | |
dc.date.accessioned | 2015-02-04T09:31:12Z | |
dc.date.available | 2015-02-04T09:31:12Z | |
dc.date.issued | 2014-08-18 | |
dc.identifier | 159775493 | |
dc.identifier | 2158ff5e-acf0-496c-88d7-a2b790f72e57 | |
dc.identifier | 000339861700027 | |
dc.identifier | 84904440448 | |
dc.identifier | 000339861700027 | |
dc.identifier.citation | Lesieur , M , Lazreg , F & Cazin , C S J 2014 , ' A cooperative Pd-Cu system for direct C-H bond arylation ' , Chemical Communications , vol. 50 , no. 64 , pp. 8927-8929 . https://doi.org/10.1039/c4cc03201b | en |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | https://hdl.handle.net/10023/6066 | |
dc.description | The authors are grateful to the Royal Society (University Research Fellowship to CSJC) for financial support. | en |
dc.description.abstract | A novel and efficient method for C-H arylation using well-defined Pd- and Cu-NHC systems has been developed. This process promotes the challenging construction of C-C bonds from arenes or heteroarenes using aryl bromides and chlorides. Mechanistic studies show that [Cu(OH)(NHC)] plays a key role in the C-H activation and is involved in the transmetallation with the Pd-NHC co-catalyst. | |
dc.format.extent | 3 | |
dc.format.extent | 1399661 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemical Communications | en |
dc.subject | Cross-coupling reactions | en |
dc.subject | Suzuki-Miyaura | en |
dc.subject | Vinyl halides | en |
dc.subject | Palladium | en |
dc.subject | Complexes | en |
dc.subject | Reagents | en |
dc.subject | Catalyst | en |
dc.subject | Substitutions | en |
dc.subject | Heteroarenes | en |
dc.subject | Activation | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | A cooperative Pd-Cu system for direct C-H bond arylation | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/c4cc03201b | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.rsc.org/suppdata/cc/c4/c4cc03201b/c4cc03201b1.pdf | en |
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