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A cooperative Pd-Cu system for direct C-H bond arylation

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c4cc03201b.pdf (1.334Mb)
Date
18/08/2014
Author
Lesieur, Mathieu
Lazreg, Faima
Cazin, Catherine S. J.
Keywords
Cross-coupling reactions
Suzuki-Miyaura
Vinyl halides
Palladium
Complexes
Reagents
Catalyst
Substitutions
Heteroarenes
Activation
QD Chemistry
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Abstract
A novel and efficient method for C-H arylation using well-defined Pd- and Cu-NHC systems has been developed. This process promotes the challenging construction of C-C bonds from arenes or heteroarenes using aryl bromides and chlorides. Mechanistic studies show that [Cu(OH)(NHC)] plays a key role in the C-H activation and is involved in the transmetallation with the Pd-NHC co-catalyst.
Citation
Lesieur , M , Lazreg , F & Cazin , C S J 2014 , ' A cooperative Pd-Cu system for direct C-H bond arylation ' , Chemical Communications , vol. 50 , no. 64 , pp. 8927-8929 . https://doi.org/10.1039/c4cc03201b
Publication
Chemical Communications
Status
Peer reviewed
DOI
https://doi.org/10.1039/c4cc03201b
ISSN
1359-7345
Type
Journal article
Rights
Copyright 2014 The Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/)
Description
The authors are grateful to the Royal Society (University Research Fellowship to CSJC) for financial support.
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  • University of St Andrews Research
URL
http://www.rsc.org/suppdata/cc/c4/c4cc03201b/c4cc03201b1.pdf
URI
http://hdl.handle.net/10023/6066

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