Isolatable organophosphorus(III)-tellurium heterocycles

Nordheider, Andreas; Chivers, Tristram; Schoen, Oliver; Karaghiosoff, Konstantin; Arachchige, Kasun S. Athukorala; Slawin, Alexandra M. Z.; Woollins, J. Derek

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dc.contributor.author	Nordheider, Andreas
dc.contributor.author	Chivers, Tristram
dc.contributor.author	Schoen, Oliver
dc.contributor.author	Karaghiosoff, Konstantin
dc.contributor.author	Arachchige, Kasun S. Athukorala
dc.contributor.author	Slawin, Alexandra M. Z.
dc.contributor.author	Woollins, J. Derek
dc.date.accessioned	2014-12-16T00:01:30Z
dc.date.available	2014-12-16T00:01:30Z
dc.date.issued	2014-01-10
dc.identifier	111957699
dc.identifier	97623c7f-8ee4-47fc-a486-06a83e74e2f3
dc.identifier	000329481800013
dc.identifier	84892369197
dc.identifier	000329481800013
dc.identifier.citation	Nordheider , A , Chivers , T , Schoen , O , Karaghiosoff , K , Arachchige , K S A , Slawin , A M Z & Woollins , J D 2014 , ' Isolatable organophosphorus(III)-tellurium heterocycles ' , Chemistry - A European Journal , vol. 20 , no. 3 , pp. 704-712 . https://doi.org/10.1002/chem.201303884	en
dc.identifier.issn	0947-6539
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/56861776
dc.identifier.other	ORCID: /0000-0002-1498-9652/work/31779200
dc.identifier.uri	https://hdl.handle.net/10023/5925
dc.description	We are grateful to the University of St Andrews, the EPSRC and NSERC Canada for their financial support.	en
dc.description.abstract	A new structural arrangement Te3(RPIII)3 and the first crystal structures of organophosphorus(III)–tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Tem(PIIIR)n (m=1: n=2, R=OMes* (Mes*=supermesityl or 2,4,6‐tri‐tert‐butylphenyl); n=3, R=adamantyl (Ad); n=4, R=ferrocene (Fc); m=n=3: R=trityl (Trt), Mesor by the installation of a PV2N2 anchor in RPIII[TePV(tBuN)(μ‐NtBu)]2 (R=Ad, tBu).
dc.format.extent	9
dc.format.extent	5424984
dc.language.iso	eng
dc.relation.ispartof	Chemistry - A European Journal	en
dc.subject	Heterocycles	en
dc.subject	NMR spectroscopy	en
dc.subject	Phosphorus	en
dc.subject	Tellurium	en
dc.subject	X-ray diffraction	en
dc.subject	QD Chemistry	en
dc.subject	BDY	en
dc.subject.lcc	QD	en
dc.title	Isolatable organophosphorus(III)-tellurium heterocycles	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	10.1002/chem.201303884
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2014-12-16

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