Isolatable organophosphorus(III)-tellurium heterocycles
Abstract
A new structural arrangement Te3(RPIII)3 and the first crystal structures of organophosphorus(III)–tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Tem(PIIIR)n (m=1: n=2, R=OMes* (Mes*=supermesityl or 2,4,6‐tri‐tert‐butylphenyl); n=3, R=adamantyl (Ad); n=4, R=ferrocene (Fc); m=n=3: R=trityl (Trt), Mesor by the installation of a PV2N2 anchor in RPIII[TePV(tBuN)(μ‐NtBu)]2 (R=Ad, tBu).
Citation
Nordheider , A , Chivers , T , Schoen , O , Karaghiosoff , K , Arachchige , K S A , Slawin , A M Z & Woollins , J D 2014 , ' Isolatable organophosphorus(III)-tellurium heterocycles ' , Chemistry - A European Journal , vol. 20 , no. 3 , pp. 704-712 . https://doi.org/10.1002/chem.201303884
Publication
Chemistry - A European Journal
Status
Peer reviewed
ISSN
0947-6539Type
Journal article
Rights
Copyright 2014, Wiley. This is the accepted version of the following article: Nordheider, A. et al (2014) ‘Isolatable Organophosphorus(III)–Tellurium Heterocycles’. Chemistry - A European Journal, Vol 20 (3) pp. 704–712, which has been published in final form at: DOI: 10.1002/chem.201303884
Description
We are grateful to the University of St Andrews, the EPSRC and NSERC Canada for their financial support.Collections
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