Isolatable Organophosphorus(III)-Tellurium Heterocycles

View/Open

Nordheider_et_al._P_Te_FullPaper.pdf (5.173Mb)

Date

13/01/2014

Abstract

A new structural arrangement Te-3(RPIII)(3) and the first crystal structures of organophosphorus(III)-tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Te-m((PR)-R-III)(n) (m=1: n=2, R=OMes* (Mes*=supermesityl or 2,4,6-tri-tert-butylphenyl); n=3, R=adamantyl (Ad); n=4, R=ferrocene (Fc); m=n=3: R=trityl (Trt), Mesor by the installation of a (P2N2)-N-V anchor in RPIII[TePV(tBuN)(-NtBu)](2) (R=Ad, tBu).

Citation

Nordheider , A , Chivers , T , Schoen , O , Karaghiosoff , K , Arachchige , K S A , Slawin , A M Z & Woollins , J D 2014 , ' Isolatable Organophosphorus(III)-Tellurium Heterocycles ' Chemistry - A European Journal , vol 20 , no. 3 , pp. 704-712 . DOI: 10.1002/chem.201303884

Publication

Chemistry - A European Journal

Status

Peer reviewed

DOI

https://doi.org/10.1002/chem.201303884

ISSN

0947-6539

Type

Journal article

Rights

Copyright 2014, Wiley. This is the accepted version of the following article: Nordheider, A. et al (2014) ‘Isolatable Organophosphorus(III)–Tellurium Heterocycles’. Chemistry - A European Journal, Vol 20 (3) pp. 704–712, which has been published in final form at: DOI: 10.1002/chem.201303884

Collections

URI

http://hdl.handle.net/10023/5925

St Andrews Research Repository