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2-Arylacetic anhydrides as ammonium enolate precursors
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dc.contributor.author | Morrill, Louis C. | |
dc.contributor.author | Ledingham, Lyndsay A. | |
dc.contributor.author | Couturier, Jean-Philippe | |
dc.contributor.author | Bickel, Jasmine | |
dc.contributor.author | Harper, Andrew D. | |
dc.contributor.author | Fallan, Charlene | |
dc.contributor.author | Smith, Andrew D. | |
dc.date.accessioned | 2014-12-11T15:31:02Z | |
dc.date.available | 2014-12-11T15:31:02Z | |
dc.date.issued | 2014-01-28 | |
dc.identifier | 112004851 | |
dc.identifier | 8fd17324-a3ad-4a21-b6d5-bf4d18f36a1d | |
dc.identifier | 000330082700011 | |
dc.identifier | 84890815687 | |
dc.identifier | 000330082700011 | |
dc.identifier.citation | Morrill , L C , Ledingham , L A , Couturier , J-P , Bickel , J , Harper , A D , Fallan , C & Smith , A D 2014 , ' 2-Arylacetic anhydrides as ammonium enolate precursors ' , Organic & Biomolecular Chemistry , vol. 12 , no. 4 , pp. 624-636 . https://doi.org/10.1039/c3ob41869c | en |
dc.identifier.issn | 1477-0520 | |
dc.identifier.other | ORCID: /0000-0002-2104-7313/work/36567515 | |
dc.identifier.uri | https://hdl.handle.net/10023/5916 | |
dc.description | This work is supported by funding from the Carnegie Trust for the Universities of Scotland and EPSRC | en |
dc.description.abstract | Readily prepared 2-arylacetic anhydrides act as convenient ammonium enolate precursors in isothiourea (HBTM-2.1)-mediated catalytic asymmetric intermolecular Michael addition-lactonisation processes, giving diverse synthetic building blocks in good yield with high diastereo- and enantiocontrol (up to 98 : 2 dr and > 99% ee). | |
dc.format.extent | 13 | |
dc.format.extent | 1493449 | |
dc.language.iso | eng | |
dc.relation.ispartof | Organic & Biomolecular Chemistry | en |
dc.subject | Dynamic Kinetic Resolution | en |
dc.subject | Tricyclic-Beta-Lactones | en |
dc.subject | Acyl Transfer Catalyst | en |
dc.subject | Silyl Ketene Acetals | en |
dc.subject | Asymmetric Organocatalysis | en |
dc.subject | Enantioselective Synthesis | en |
dc.subject | Carboxylic Anhydrides | en |
dc.subject | Gamma-Butyrolactones | en |
dc.subject | C-Acylation | en |
dc.subject | Keto Acids | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | 2-Arylacetic anhydrides as ammonium enolate precursors | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/c3ob41869c | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | UF090013 | en |
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